1. Determine the relationship between the two structures below. Circle your answer. H. Br H H CH3 H (CH3)3C-H CI-CI AH°-400 kJ/mol AH° 243 kJ/mol Br + (a) Enantiomers (b) Diastereomers 2. The bond dissociation energies for the relevant bonds are given below. Calculate the overall AHⓇ for the reaction. Place your answer in the box without units. (c) Identical (d) Constitutional isomers → (CH3)3C-CI + H-CI AH°-349 kJ/mol AH-432 kJ/mol kJ/mol

1. Determine the relationship between the two structures below. Circle your answer. H. Br H H CH3 H (CH3)3C-H CI-CI AH°-400 kJ/mol AH° 243 kJ/mol Br + (a) Enantiomers (b) Diastereomers 2. The bond dissociation energies for the relevant bonds are given below. Calculate the overall AHⓇ for the reaction. Place your answer in the box without units. (c) Identical (d) Constitutional isomers → (CH3)3C-CI + H-CI AH°-349 kJ/mol AH-432 kJ/mol kJ/mol

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter5: Stereochemistry At Tetrahedral Centers

Section5.SE: Something Extra

Problem 70AP

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