1.065 g of stainless steel was dissolved in hydrochloric acid (chromium as Cr 3+ ) and diluted to 500.0 ml. A 50.00 ml sample was passed through a Walden reducer, where only iron is reduced (Fe3+ + e- Fe2+), and titrated with 0.01920 M KMnO4 solution, which consumed 13.72 ml. A 100.0 ml sample was passed through a Jones reducer (Cr3+ + e- Cr2+ and Fe3+ + e- Fe2+) into 50.00 ml of a 0.1000 M Fe3+ solution. The resulting solution was titrated with 0.01920 M KMnO4 solution and 36.43 ml was consumed. Calculate the Fe and Cr concentrations of the sample in weight percent.
1.065 g of stainless steel was dissolved in hydrochloric acid (chromium as Cr 3+ ) and diluted to 500.0 ml. A 50.00 ml sample was passed through a Walden reducer, where only iron is reduced (Fe3+ + e- Fe2+), and titrated with 0.01920 M KMnO4 solution, which consumed 13.72 ml. A 100.0 ml sample was passed through a Jones reducer (Cr3+ + e- Cr2+ and Fe3+ + e- Fe2+) into 50.00 ml of a 0.1000 M Fe3+ solution. The resulting solution was titrated with 0.01920 M KMnO4 solution and 36.43 ml was consumed. Calculate the Fe and Cr concentrations of the sample in weight percent.
Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter22: The Chemistry Of The Transistion Elements
Section22.6: Colors Of Coordination Compounds
Problem 3Q
Related questions
Question
1.065 g of stainless steel was dissolved in hydrochloric acid (chromium as Cr 3+ ) and diluted to 500.0 ml. A 50.00 ml sample was passed through a Walden reducer, where only iron is reduced (Fe3+ + e- Fe2+), and titrated with 0.01920 M KMnO4 solution, which consumed 13.72 ml. A 100.0 ml sample was passed through a Jones reducer (Cr3+ + e- Cr2+ and Fe3+ + e- Fe2+) into 50.00 ml of a 0.1000 M Fe3+ solution. The resulting solution was titrated with 0.01920 M KMnO4 solution and 36.43 ml was consumed. Calculate the Fe and Cr concentrations of the sample in weight percent.
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 4 steps with 3 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning
General Chemistry - Standalone book (MindTap Cour…
Chemistry
ISBN:
9781305580343
Author:
Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:
Cengage Learning