1. (a) Complete the sequence of reaction products A, B, C, D belowwithout any mechanisms being given.H,SO,конBrheatBD40 °C30 °CK,CO 3/acetone(i)(ii) Draw a mechanism for the conversion of C to DS. (a) Explain what is meant by the term: "heteronuclear" electrophilicsubstitution with respect to naphthalene derivatives.(b) Which of the following will readily participate in such reaction?(c) Use resonance structures to illustrate which positions would bepreferred, from atheoretical point of view during such reaction.онFON

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1.(a) Complete the sequence of reaction products A, B, C, D below without any mechanisms being given. H, SO, кон BI heat A D 40°C 30 °C K,CO 3/acetone (i) (ii) Draw a mechanism for the conversion of C to D

1.(a) Complete the sequence of reaction products A, B, C, D below without any mechanisms being given. H, SO, кон BI heat A D 40°C 30 °C K,CO 3/acetone (i) (ii) Draw a mechanism for the conversion of C to D

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter11: Reactions Of Alkyl Halides: Nucleophilic Substitutions And Eliminations

Section11.SE: Something Extra

Problem 76AP

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Concept explainers

Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.

Question

1. (a) Complete the sequence of reaction products A, B, C, D below
without any mechanisms being given.
H,SO,
кон
Br
heat
B
D
40 °C
30 °C
K,CO 3/acetone
(i)
(ii) Draw a mechanism for the conversion of C to D
S. (a) Explain what is meant by the term: "heteronuclear" electrophilic
substitution with respect to naphthalene derivatives.
(b) Which of the following will readily participate in such reaction?
(c) Use resonance structures to illustrate which positions would be
preferred, from a
theoretical point of view during such reaction.
он
FON

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