17. Write a series of equations to illustrate the synthesis of 3-pentanone from an alkene (you must choose the correct alkene compound to begin your series of reactions). Include the names and structures of all reactants and products. (3T/I, 3C)
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- (a) 2-methyl-2-pentanol Draw the structure of the alkene that was used to prepare the alcohol in highest yield. AAVIL ? ChemDoodleⓇ Which process does this employ? 1. Hg(OAc)2, H₂O; 2. NaBH4 01. BH3; 2. H₂O2, NaOH OsO4, H₂O2 On n [ ]#33. Consider the reaction scheme below: CH;CHO A CH;MgBr D B CH,CN CH3COOH Y 1. Dry ether 2. H30* E CH;COOCH2CH3 CH3COCI NH3 a) Draw the structural formulae for X, Y and Z b) State the reagent(s) and condition(s) for A, B, C, D and EDraw the line-angle formula of the enol formed in the following alkyne hydration reaction and then draw the structural formula of the carbonyl compound with which this enol is in equilibrium. -C=CH 1. (sia)2BH 2. NaOH/H₂O₂ an enol carbonyl compound • You do not have to consider stereochemistry. • Draw both the enol and the carbonyl forms. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate structures using the sign from the drop-down menu. ChemDoodleⓇ <
- 3. Write the structure of the alkene X, that forms the compound below, when treated with ozone (O3) and Zn and Acetic Acid or (CH3)2S workup. X=? X+ (1) Ozone + (2) Zn, Acetic Acid CH2-1- Pentyne frome bromo Propan. Give The IUPAC Name for the following Compounds CH3 C2 HS 3,ct3CH=CH-CHz -CH3 4 CH),-CH - C =CH CH3 * CH3- -CH2-¢=CH2 CH3 C43 Qn Prefare The Pollowing ComPounds 1. Iso propyl Alcohel from popelene. 3. Acetaldehyde fram Acetylene- from propene- y. 1,2- Di bromo Propan * Iso buty) chloride from Isobutan . -Good Luck- Seanned by TapScanneDraw a structural formula for an alkene with the indicated molecular formula that gives the compound shown as the major product (more than one alkene may give the same compound as the major product). ribed Text (b) CgH14+ Brg (c) C6H12 (d) C6H12 1. BH₂ 2. H₂O2, NaOH 1. Hg(OAc)2, H₂O 2. NaBH4 Br Br OH 3 LOH C
- 7) You want to synthesize 3-methyl-2-pentene from 2-chloro-3-methylpentane. Which reagent would you use? a. HCI, heat b. NH:(aq), 25°C c. CH:CO2NA, CH:CO2H, heat d. CH3CH2ONA, CH3CH2OH, heat e. CН:CH2ОН, heatFor the following compounds; CH3 CI. H CH3 Cl H. H CI J K i) Assign (R) or (S) designation to each of the following compounds and show the correct priority order. ii) State the IUPAC name for compound I, J and K.10:29 0. O ? 86% AIATS For Two Year Medic. A 61 /180 (02:55 hr min Mark for Review When 2-Methylpropene undergoes oxidation in the presence of acidic K2Cr2O7, the products obtained are CH3 – CH + CO2 CH3 — СH — С—ОН-СО, CH, -C =0+CO2 +H2O CH3 CH; – CH2 – CH + CO2 + H20 Clear Response III
- Which reaction would yield cyclopentanol? سیدگی (A) (B) -d (C) (D) 1. LiAlH4 2. H+ 1. NaBH4 2. H+ 1. BHg:THF 2. H2O2, NaOH OSO4Consider the substitution reaction of (R)-3-chloro-3-methylhexane with methanol and heat. H₂C- CH₂ H₂C H₂C Cl CH₂ D No Reaction MeOH Identify the substitution product(s). A a H₂C с H₂C НО CH₂ CH₂ CH₂ B H₂C D H₂C H₂C OH H₂C O CH₂ -CH₂ CH₂Predict the major product in each of the following reactions. Name the alkene reactant and the product, using IUPAC nomenclature. a. CH3 H Ni H C=C CH3 + H₂ H+ b. (CH,),C=CHCH,CH,CH, + H,O c. (CH3)₂C=CHCH3 + Br₂ ? d. CH3C(CH3)₂CH=CH₂ + HCl →? ?