2. Fill in the boxes in the following problem. (Hints: The difference between the # of carbonsin the product and the # in the starting material tells us the # in the carbonyl. The fact that weform only one product tells us the identity of the carbonyl.)C8H9Br1H NMR: 7.3-7.1 (m, 5H)3.5 (t, 2H)3.1 (t, 2H)1) Ph3P2) nBuLiphosphonium ylidecarbonylC1114(only one product formed)

The missing reactant, reagents and product has find with proper explanation. Also we have provided…

Answered: 2. Fill in the boxes in the following…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Reaction of p-cresol with two equivalents of 2-methylprop-1-ene affordsBHT, a preservative with molecular formula C15H24O. BHT gives thefollowing 1H NMR spectral data: 1.4 (singlet, 18 H), 2.27 (singlet, 3 H), 5.0(singlet, 1 H), and 7.0 (singlet, 2 H) ppm. What is the structure of BHT?Draw a stepwise mechanism illustrating how it is formed.
Which of the following reagent best accomplish this transformation below? a. Li/NH3 b. H2SO4, H2O, HgSO4 c. BH3, THF d. potassium permanganate
How many signals would the product of the following reaction show in a. its 1H NMR spectrum? b. its 13C NMR spectrum?
Predict the product based on the following data: H-NMR: 0.93 ppm (3H, triplet); 1.57 ppm (2H, multiplet – looks like “pentet”); 2.14 ppm (3H,singlet), 2.26ppm (2H, triplet); 3.42 ppm (1H, triplet); 4.83 ppm (1H, multiplet) Weight of product: 156 g/mol IR: Two sharp peaks at 1784 cm-1 and 1742 cm-1 C-NMR: 9.9 ppm; 29.0 ppm; 29.8 ppm; 31.8 ppm; 52.9 ppm; 76.1 ppm; 181.1 ppm; 200.2 ppm
Which of the following reagent best accomplish this transformation below? a. H2, Lindlar b. BH3, THF c. Li/NH3 d. NaNH2, NH3
Reaction of C6H5CH2CH2OH with CH3COCl affords compound W, whichhas molecular formula C10H12O2. W shows prominent IR absorptions at3088–2897, 1740, and 1606 cm−1. W exhibits the following signals in its1H NMR spectrum: 2.02 (singlet), 2.91 (triplet), 4.25 (triplet), and 7.20–7.35(multiplet) ppm. What is the structure of W?
Reaction of (CH3)3CCHO with (C6H5)3P=C(CH3)OCH3, followed by treatment with aqueous acid, affords R (C7H14O). R has a strong absorption in its IR spectrum at 1717 cm−1 and three singlets in its 1H NMR spectrum at 1.02 (9 H), 2.13 (3 H), and 2.33 (2 H) ppm. What is the structure of R? We will learn about this reaction in Chapter 18.
As we will learn in Chapter 20, reaction of (CH3)2CO with LiC ≡ CH followed by H2O affords compound D, which has a molecular ion in its mass spectrum at 84 and prominent absorptions in its IR spectrum at 3600–3200, 3303, 2938, and 2120 cm. D shows the following 1H NMR spectral data: 1.53 (singlet, 6 H), 2.37 (singlet, 1 H), and 2.43 (singlet, 1 H) ppm. What is the structure of D?
As we will learn in Chapter 17, reaction of (CH3)2CO with LIC≡CH followed by H2O affords compound D, which has a molecular ion in its mass spectrum at 84 and prominent absorptions in its IR spectrum at 3600−3200, 3303, 2938, and 2120 cm−1. D shows the following 1H NMR spectral data: 1.53 (singlet, 6 H), 2.37 (singlet, 1 H), and 2.43 (singlet, 1 H) ppm. What is the structure of D?
A substituted styrene derivative has the following 'H NMR data: 1H NMR (CDCI3, 400 MHz) 8 8.37 (d, 2H), 8.03(d, 2H), 6.86 (dd, 1H), 6.05 (d, 1H), 5.55 (d, 1H). The structure of styrene itself is C6HsCH=CHz. Which styrenederivative is it? which one is it 2-Fluorostyrene2-Nitrostvrene4-Fluorostyrene 3-Hydroxystyrene4-Nitrostyrene
Provide the suitable reagents to effect the following transformations. I specifically need help on sub-parts d, e, f, g, h, and i.
Determine the reagents A, B, C, D, E and the structure of compounds I, II, II in the reaction below

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