2. Show that in the canonical (T –V – N) ensemble (E – E)(P – P) = -(ðP/Əß)v,N = KT²(ƏP/ƏT)v,N , where B ensemble averages. 1/(kT), and bars (or overlines) above symbols or expressions mean canoni

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2. Show that in the canonical (T – V – N) ensemble
(E – E)(P – P) = -(@P/aB)v,N = kT²(ƏP/ƏT)v,n ,
where B =
ensemble averages.
1/(kT), and bars (or overlines) above symbols or expressions mean canonical-
Transcribed Image Text:2. Show that in the canonical (T – V – N) ensemble (E – E)(P – P) = -(@P/aB)v,N = kT²(ƏP/ƏT)v,n , where B = ensemble averages. 1/(kT), and bars (or overlines) above symbols or expressions mean canonical-
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