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- Which of the following structures and IUPAC names are incorrectly matched? * oe (A) Methyleyclohexanoate (В) `NH2 Br 4-Bromo-3-chlorohexanamide 2-Ethoxypentane (D) HOOC HOOC 3,5-Nonanedioic acid В A DDraw the correct structure(s) for the organic product or products in each of the following reactions H OH A) OH B) H-C-CH₂-CH₂- D) TA 0 H* O= Heat CH₂ cufat. C) CH₂-C- CH₂ ?? + H₂O [0] Draw the Aldehyde and the Carboxylic Acid NaBH CH₂-CH₂-CH₂-OH ?? ?? - H₂0 ?? ??What reaction took place in the reaction below? CHẠCH, CH; CH,(CH),CH; CH{CH,),C-OCH; CHẠCH)A CH; CHỊCHCo H0 НОСН CH/CH),CH, CH, (CH),C-C HOCH, HH O reduction (hydrogenation) O amide synthesis O acetal hydrolysis O ester synthesis O acid base O dehydration O thioester synthesis O phosphate ester synthesis O hydration O ester hydrolysis O amide hydrolysis O oxidation O acetal synthesis
- 1 2 3 4 5 6 Cr₂03 Base RX 1 o= KNO3 H₂SO4 4 5- Isatoic Nitroisatin anhydride carbonyl O N- Alkyl isatin compound HCI/Zn 2 3 quinoline 4- carboxyl acidCollege Chem II CHE 132 Ch. 16 - CarboOxylic Acids & Esters 1. Draw the structure of the product that forms in each reaction. Name the reactants and the products (organic compounds only.) a) Ho-C-ct, CH CHy + NaoH - 7 City b) CHyOH + -OH + Hbo ecid ) Cig-と-0-S4-cns NaCH e) Cg-C-と-cy Ot stree + CaloH) f)COOH O 3-carboxytoluene 3-methylcyclohexanecarboxylic acid O m-methylbenzoic acid 3-toluenebenzoic acid f5 f6 %23 17 & 7 Q W R T Y # M
- Draw the major product of the reaction between 1-butanol and Na2Cr207, H2SO4, H2O. O, O, e CHHO HO. OH base CI EIO- C-OEt epichlorohydrin OH NaOEt 2,6-dihydroxy- acetophenone *Na O2C. .CO2 Na* NaOH, H2O II OH Cromolyn sodium Cromolyn sodium, developed during the 1960s, has been used to prevent allergic reactions primarily affecting the lungs, as, for example, exercised- induced emphysema. It is thought to block the release of histamine, which prevents the sequence of events leading to swelling, itching, and constriction of bronchial tubes. v Cromolyn sodium is synthesized in the above series of steps. rch 31% 11:24 P 4/20/20-Which one of the following is NOT a possible completion of the following reaction? CH,OH но но 1. NABH, 2. acidic workup но H- OH ČH,OH A. D-talose B. D-tagatose C. the C-3 epimer of D-gulose D. the C-5 epimer of L-psicose E. the C-5 epimer of L-allose F. the C-3 epimer of D-idose G. g. the C-3 epimer of L-glucose A В E F O G
- Complete the given reactions by drawing the structures of the major organic products: Please draw the completed reaction OH HO HOCN H₂N H₂O H3PO4 OH HO HO. (excess) H3O+ H2SO4 H*EtO n Arrow-pushing Instructions EtO. OEt EtO: H3C >XT OEt 1. NaOEt, EtOH 2. H3O+ In the mixed Claisen condensation, the donor and target molecules are different. The target molecule is chosen as one that does not contain an acidic a-carbon. The donor molecule, as in the case of the standard Claisen condensation, is one that has more than one acidic a-hydrogen. The mechanism for the mixed Claisen condensation proceeds as for the standard reaction: nucleophilic attack of the enolate anion on the carbonyl group of the target, expulsion of the weakest base, deprotonation to drive the equilibrium forward, and subsequent protonation to give the final product. Draw curved arrows to show the movement of electrons in this step of the mechanism. EtO. the file OEt OEt H H H EtO. O OEt + EtOH EtOHa) b) Complete the following reactions: c) OH он + хон сле НО OH OH H₂SO, А H₂SO, H₂SO OH або два H_SO. d) OH Д
