3+ When a certain strong-field ligand forms an octahedral complex with Mn³ cation, the energies of the valence d orbitals on the manganese atom are split according to this electron box diagram: energy in kJ/mol -300 -350 -400 -450 -500 -550 -600 -650 -700 -750 xy 2 z 22 x -y yz xz Using this diagram, answer the following questions. How many unpaired d electron spins does the manganese atom have? Is the complex paramagnetic or diamagnetic? Predict the color of the complex. O paramagnetic O diamagnetic O blue or green O red or violet O orange or yellow Owhite or transparent +
3+ When a certain strong-field ligand forms an octahedral complex with Mn³ cation, the energies of the valence d orbitals on the manganese atom are split according to this electron box diagram: energy in kJ/mol -300 -350 -400 -450 -500 -550 -600 -650 -700 -750 xy 2 z 22 x -y yz xz Using this diagram, answer the following questions. How many unpaired d electron spins does the manganese atom have? Is the complex paramagnetic or diamagnetic? Predict the color of the complex. O paramagnetic O diamagnetic O blue or green O red or violet O orange or yellow Owhite or transparent +
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
Problem 31P
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Atomic Structure
The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.
Shape of the D Orbital
Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.
Question
Transcribed Image Text:3+
When a certain strong-field ligand forms an octahedral complex with Mn cation, the energies of the valence d orbitals on the manganese atom are split
according to this electron box diagram:
energy in kJ/mol
-300
-350
-400
-450
-500
-550
-600
-650
-700
-750
xy
2
x -y
yz
xz
Using this diagram, answer the following questions.
How many unpaired d electron spins does the manganese atom
have?
Is the complex paramagnetic or diamagnetic?
Predict the color of the complex.
0
O paramagnetic
O diamagnetic
O blue or green
O red or violet
O orange or yellow
O white or transparent.
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