4.35 Formulate the reaction of cyclohexene with (i) Br2 and (ii) meta-chloro-peroxybenzoic acid followed by H30+. Show the reaction intermediatesand the final products with correct cis or trans stereochemistry.4.36 What products would you expect to obtain from reaction of cyclohexa-1,3-diene with each of the following?(a) 1 mol Br2 in CH2C12(c) 1 mol DCl (D = deuterium, ²H)(b) 1 mol HCl(d) 2 mol H2 over a Pd catalyst4.37 Predict the products of the following reactions on hex-1-yne:(a) 1 equiv HBr?(b) 1 equiv Cl2?(c) H2, Lindlar catalyst

the reaction of cyclohexene with Br2 is followed by anti addition to give trans product having a…

4.35 Formulate the reaction of cyclohexene with (i) Br2 and (ii) meta-chloro- peroxybenzoic acid followed by H30+. Show the reaction intermediates and the final products with correct cis or trans stereochemistry.

4.35 Formulate the reaction of cyclohexene with (i) Br2 and (ii) meta-chloro- peroxybenzoic acid followed by H30+. Show the reaction intermediates and the final products with correct cis or trans stereochemistry.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter14: Conjugated Compounds And Ultraviolet Spectroscopy

Section14.SE: Something Extra

Problem 50AP: -Ocimene is a pleasant-smelling hydrocarbon found in the leaves of certain herbs. It has the...

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Concept explainers

Alkynes

Alkynes are organic compounds that contain at least one triple bond between carbon-carbon atoms. They are a series of unsaturated compounds with a general molecular formula, CnH2n-2.

Question

4.35 Formulate the reaction of cyclohexene with (i) Br2 and (ii) meta-chloro-
peroxybenzoic acid followed by H30+. Show the reaction intermediates
and the final products with correct cis or trans stereochemistry.
4.36 What products would you expect to obtain from reaction of cyclohexa-
1,3-diene with each of the following?
(a) 1 mol Br2 in CH2C12
(c) 1 mol DCl (D = deuterium, ²H)
(b) 1 mol HCl
(d) 2 mol H2 over a Pd catalyst
4.37 Predict the products of the following reactions on hex-1-yne:
(a) 1 equiv HBr
?
(b) 1 equiv Cl2
?
(c) H2, Lindlar catalyst

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