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- Give the organic product: OA OB OC NO₂ A CI 6 NO₂ NO₂ B + CH,-SH S-CH; CH3-$ C ? S-CH; DOH - NH, Br2/KOH →product; 1. (a-hydroxy amide) Product of this Hoffmann bromamide reaction is : OH (a) Ph – Ĉ-CH3 (Ъ) Ph — CHO (c) Ph- CH3 (d) Ph – CH2 -NH2 NO2Identify the type of mechanism for the following reaction: NaOEt ELOH, A OEt (A) Addition-elimination mechanism (B) Benzyne mechanism (C) Elimination-addition mechanism (D) By SN² displacement
- 14) What is the major organic product of each of the following reactions? + H,N-NH-Ph H* + 2 CH,OH + LIAIH(O-t-Bu); + (CH;CH,),CULİH11.32 - Level 2 :: Unanswered • 3 attempts left What is the major product of the following reaction? A A В В C D D E E H Et Br NaOCH; HOCH H. Et Et Et H H OMe Et Racemic Mixture в H Et OMe HIdentify the product of the following reaction; axidation ? OH но.
- (c) 1 Unambiguously identify the structures of the following major organic product(s), starting materials (reactants), or reagents for the following reactions Draw all possible stereoisomers (") where necessary; double-dagger (1) must show two products: (b)* d)* (a) OH o. I (excess) R I. HO & OH OH H НО OH H₂O (excess) [H"] [H')/-(H₂O) [H1/H₂01 Br₂/H₂O* pH =6What is the best description of the product distribution from the reaction shown (- OTF=triflate, trifluoromethanesulfonate) Na OH,coo CH, COOHH,0 C D. DA mixture of compounds B and D OA mixture of compounds A and C OA mixture of compounds A and B OA mixture of compounds A and D(a) Provide the missing reagents and line structures of the products (C- E) for the following reactions. Include stereochemistry for products Cand E as indicated. No mechanisms are required. (5) C H,0 Show stereochemistry any one diastereomer OH PCC. CH;Cla D H. Pd/C Show stereochemistry any one enantlomer
- Reaction of acetic acid, CH3CO2H, with isotopically labeled CH318OH and catalytic sulfuric acid gives: 180 A) CH;COCH; + H2O CH;C "OCH; + H,0 180 II C) CH;COCH3 + H¿®O D) equal amounts of A and BGive appropriate name for each of the following compounds: (a) Rh(n5-Cp)(n?-C2H4)(PME3) (b) -py Rh -CEC-ph Ph3PWhat is the expected major product for the following reaction sequence? OH OH + enantiometr 01 00 0 || OIV OV OsO4 (cat.) NMO 애 OH + enantiomer 11 OH + enantiomer ||| IV مة HO OH