5- A water sample has a total alkalinity of 220 mg/l and has a pH of 7.4. The maximum amount of calcium ion is found when the solubility product of CaCO3, K, = [Ca"I [CO,]= 4.57x10", is met. For natural water, %D Talk+[H*]-k/[H*] [HCO, ]= 1+2k, /[H*] Talk+[H]-k,[H*] 2(1+[H*/2k,) kw= [H'] [OH] k2= [H'] [CO,"] /[HCO,]= 4.69x10" [CO, = Calculate the maximum amount of calcium ion in mg/l as CaCO3 that could be contained in a solution at equilibrium at 25 °C.

Chemistry: Principles and Reactions
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Author:William L. Masterton, Cecile N. Hurley
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Chapter15: Complex Ion And Precipitation Equilibria
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5- A water sample has a total alkalinity of 220 mg/l and has a pH of 7.4. The maximum
amount of calcium ion is found when the solubility product of CaCO3, K, = [Ca I
[CO, ] = 4.57x10", is met. For natural water,
Talk+[H*]-k,/[H*]
1+2k, /[H*]
Talk+[H ]-k,MH*]
2(1+[H*V2k;)
kw= [H*] [OH]
k2= [H'] [CO,"] /[HCO,]=4.69x 10"
[HCO, ]=
[CO, ]=
Calculate the maximum amount of calcium ion in mg/l as CaCO3 that could be
contained in a solution at equilibrium at 25 C.
Transcribed Image Text:5- A water sample has a total alkalinity of 220 mg/l and has a pH of 7.4. The maximum amount of calcium ion is found when the solubility product of CaCO3, K, = [Ca I [CO, ] = 4.57x10", is met. For natural water, Talk+[H*]-k,/[H*] 1+2k, /[H*] Talk+[H ]-k,MH*] 2(1+[H*V2k;) kw= [H*] [OH] k2= [H'] [CO,"] /[HCO,]=4.69x 10" [HCO, ]= [CO, ]= Calculate the maximum amount of calcium ion in mg/l as CaCO3 that could be contained in a solution at equilibrium at 25 C.
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