5. Which of the following "isomeric" polymers would you expect to exhibit the greater crystallinity? Explain. Chemical Structure and Polymer Morphology 8. Which of the following "isomeric" polymers would you expect to exhibit the greater crystallinity? Expl (a) CH₂CH₂CH- or CH₂CH OCH.] (b) CH, [ECH). COCH, Jon of CH₂ (c) -CH₂CF₂ or or -CHFCHF- [EICH, EOCH.CHCH,Of CH₂CH₂ 9. When poly(tetramethylene adipate) (a polymer of interest for "crystallinity initially increases surgical sutures) i jected to hydrolytic or enzymatic degradation, the polymer's percent does this suggest about the degradation process? (A.-C. Albertson and O. Ljunquist, J. Macromo Chem.. A23, 393, 1986) 10. One method of determining percent crystallinity in a polymer involves inverse gas chromatograph is, the polymer in question is used as the stationary liquid phase coated on the column packing. Sp

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
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Chapter23: Organic Polymers, Natural And Synthetic
Section: Chapter Questions
Problem 51QAP
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5. Which of the following "isomeric" polymers would you
expect to exhibit the greater crystallinity? Explain.
Chemical Structure and Polymer Morphology
8. Which of the following "isomeric" polymers would you expect to exhibit the greater crystallinity? Expl
(a) CH₂CH₂CH-
CH₂CH
or
OCH
[EICH, EOCH.CHCH₂Of
9. When poly(tetramethylene adipate) (a polymer of interest for at crinity initially increases
surgical sutures) i
jected to hydrolytic or enzymatic degradation, the polymer's percent
does this suggest about the degradation process? (A.-C. Albertson and O. Ljunquist, J. Macromo
Chem., A23, 393, 1986)
(b)
CH,
[ECH). COCH, Jon Of
CH₂
(c) -CH₂CF₂
or
or -CHFCHF-
10. One method of determining percent crystallinity in a polymer involves inverse gas chromatograph
is, the polymer in question is used as the stationary liquid phase coated on the column packing. Sp
Transcribed Image Text:5. Which of the following "isomeric" polymers would you expect to exhibit the greater crystallinity? Explain. Chemical Structure and Polymer Morphology 8. Which of the following "isomeric" polymers would you expect to exhibit the greater crystallinity? Expl (a) CH₂CH₂CH- CH₂CH or OCH [EICH, EOCH.CHCH₂Of 9. When poly(tetramethylene adipate) (a polymer of interest for at crinity initially increases surgical sutures) i jected to hydrolytic or enzymatic degradation, the polymer's percent does this suggest about the degradation process? (A.-C. Albertson and O. Ljunquist, J. Macromo Chem., A23, 393, 1986) (b) CH, [ECH). COCH, Jon Of CH₂ (c) -CH₂CF₂ or or -CHFCHF- 10. One method of determining percent crystallinity in a polymer involves inverse gas chromatograph is, the polymer in question is used as the stationary liquid phase coated on the column packing. Sp
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