6) Draw the structure of the products 23 to 27.tBuOHHOH,SO,231) NaBH42) H20PB132524H20, H2SO4OMeMEOHOHKHH2SO,2627

Step 1: Acid catalyzed ether formation. Step 2: ketone reduction to alcohol using NaBH4. Step 3:…

Answered: 6) Draw the structure of the products…

6) Draw the structure of the products 23 to 27. tBuOH HO H,SO4 23 1) NABH4 2) H20 PBr3 25 24 H20, H2SO, OMe MeOH OH KH H2SO, 26 27

Introduction to General, Organic and Biochemistry

11th Edition

ISBN:9781285869759

Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Chapter20: Carbohydrates

Section: Chapter Questions

Problem 20.66P

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Concept explainers

Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.

Question

6) Draw the structure of the products 23 to 27.
tBuOH
HO
H,SO,
23
1) NaBH4
2) H20
PB13
25
24
H20, H2SO4
OMe
MEOH
OH
KH
H2SO,
26
27

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