2 76PRACTICAL SPECTROSCOPYCompound 18 is a high-boiling liquid (boiling point 256' C) which is slightly soluble in water. The peak at 3.9 ppm in the 'HNMR diseppears if the compound is exposed to D,0. The Mass, IR, end 'HNMR speetra, along with 1C NMR data, are given below,Elemental Analysis: C. 71.03; H, 7.95; 0, 21.03. sto iiny pointNASS Spectru→Ct aratysthe cs thatOre laheled107152100 D 20030 tD s0 0 7 n s0 10: tio 12n 120 140 132 1ED 170Iufrared SpecirumWave Number, um 14000B i 120 1100 1001214Vieuciength, micronsH NMRStructare:C Spectral Data:singlet, 137,2 ppam:doublet, 128.4 ppm:doublet, 127.6 pprm;doublet, 127.5 ppm,trigiet, 81.6 ppm:triplet. 79.5 ppm;tmplel, 67.1 ppmC2000 Brks Cole Pubisting Compary

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76 PRACTICAL SPECTROSCOPY Compound 18 is a high-boiling liquid (boiling point 256 C) which is slighily soluble in water. The poak at 3.9 ppm in the 'H NMR dissppears if the compound is exposed to D,0. The Mass, IR, end H NMR sprctra, along with "C NMR data, are given below. Elemental Analysis: C. 71.03; H, 795; 0, 21.03. stoiting peint Alast Spectrum st oratys the cres that Ove laheld 12 50 o0 1110 120 1 140 1 40 e 10 1 200 eva Tatrared Spectrum Wave Numter, 1 400 100 e 11 14 Wavelengh, micons H NMR FEm. "C Spectral Data: Strecture: singlet, 137.2 ppan, doublet, 128.4 ppm; doublet, 127.6 ppm; doublet, 127.5 ppm, triplet, 81.6 ppm; triplet, 79.5 ppm; iriplet, 67.1 ppm Cale Pubating Cpany Intensity

76 PRACTICAL SPECTROSCOPY Compound 18 is a high-boiling liquid (boiling point 256 C) which is slighily soluble in water. The poak at 3.9 ppm in the 'H NMR dissppears if the compound is exposed to D,0. The Mass, IR, end H NMR sprctra, along with "C NMR data, are given below. Elemental Analysis: C. 71.03; H, 795; 0, 21.03. stoiting peint Alast Spectrum st oratys the cres that Ove laheld 12 50 o0 1110 120 1 140 1 40 e 10 1 200 eva Tatrared Spectrum Wave Numter, 1 400 100 e 11 14 Wavelengh, micons H NMR FEm. "C Spectral Data: Strecture: singlet, 137.2 ppan, doublet, 128.4 ppm; doublet, 127.6 ppm; doublet, 127.5 ppm, triplet, 81.6 ppm; triplet, 79.5 ppm; iriplet, 67.1 ppm Cale Pubating Cpany Intensity

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter14: Mass Spectrometry

Section: Chapter Questions

Problem 14.37P

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