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- Under certain reaction conditions, 2,3-dibromobutane reacts with twoequivalents of base to give three products, each of which contains twonew π bonds. Product A has two sp hybridized carbon atoms, product Bhas one sp hybridized carbon atom, and product C has none. What arethe structures of A, B, and C?Resveratrol is an antioxidant found in the skin of red grapes. Itsanticancer, anti-inflammatory, and various cardiovascular effects areunder active investigation. (a) Draw all resonance structures for theradical that results from homolysis of the OH bond shown in red. (b)Explain why homolysis of this OH bond is preferred to homolysis ofeither OH bond in the other benzene ring.What are the most likely products of a reaction between CH3CH2NH3 and H2O? a. CH3CH2NH3++OH b. (CH3)2NH2++OH c. CH3CH2NH2OH+H+ d. (CH2)NH2+H3O+
- Rank the following according to INCREASING reactivity towards SN2: 1st (least reactive)? 2ND? 3RD? 4TH (most reactive)?What are the possible constitutional isomers and rank by SN2 reaction.1. The of alka zeltzer in iced water will give a result and observation of _________. alka zetltzer dissolved readily alka zeltzer partially dissolved No reaction 2. In the Le Chatelier's Principle, Co(H2O)6 with oxidation of +2 is _________ in color. blue violet pink
- The purine heterocycle occurs commonly in the structure of DNA.a.How is each N atom hybridized? b.In what type of orbital does each lone pair on a N atom reside? c.How many π electrons does purine contain? d.Why is purine aromatic?Answer the following questions for the MOs of 1,3-butadiene: a. Which are pie bonding MOs, and which are p* antibonding MOs? b. Which MOs are symmetric, and which are antisymmetric? c. Which MO is the HOMO and which is the LUMO in the ground state? d. Which MO is the HOMO and which is the LUMO in the excited state? e. What is the relationship between the HOMO and the LUMO and symmetric and antisymmetric orbitals?Suzuki coupling of aryl iodide A and vinylborane B affords compound C,which is converted to D in the presence of aqueous acid. Identifycompounds C and D and draw a stepwise mechanism for the conversionof C to D.
- a. A b. B c. C d. NietherBromoetherification, the addition of the elements of Br and OR to adouble bond, is a common method for constructing rings containingoxygen atoms. This reaction has been used in the synthesis of thepolyether antibiotic monensin (Problem 18.34). Draw a stepwisemechanism for the following intramolecular bromoetherification reaction.Ethers can be prepared by reaction of an alkoxide or phenoxide ion with aprimary alkyl halide. Anisole, for instance, results from reaction of sodiumphenoxide with iodomethane. What kind of reaction is occurring? Show themechanism.
