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- One of the CHEM3341 student Ms. Fatima Al Wahaibi wanted to analyse phosphate ion concentration in Fertilizer industry wastewater sample collected from Rusayl Industrial Estate using spectrophotometer method. She mixed 200.00 mL of wastewater sample which contains only Na;PO, (unknown molarity) with 400.00 mL of 0.0200 M K,PO4 in a one liter beaker to make a Solution A. She then transferred 25.00 mL of Solution A to a 250.00 mL volumetric flask and added distilled water up to the calibration mark to make up Solution B. The Concentration of phosphate ions in Solution B is known to contain 3.00 x 103 mol/L from the spectrophotometric analysis at 460 nm using 1 cm cuvette. Calculate the concentration of phosphate ion in wastewater and how many phosphate ions are present in this wastewater.Extraction of DNA involves the use of a 1 M phosphate buffer (1-liter volume) having the hydrogen ion concentration of 6.165950019 x 10-9 M. Three pKa of phosphoric acid are available Concentrated phosphoric acid (85% w/w; Sp. Gr. = 1.70; MW = 98 g/mol) Sodium dihydrogen phosphate monohydrate (MW = 138g/mol) Sodium biphosphate heptahydrate (MW = 268g/mol) Tribasic sodium phosphate monohydrate (MW = 182 g/mol) Sodium hydroxide pellets (40 grams/mol) Question: What is the pH of the solution? (answer in two decimal places) How much of the weak acid component should be used? (Note for answer: Round to the nearest hundredth and include the unit such as "grams or milliliters"; Ex. 100.00 grams or 100.00g for weight & 100.00 milliliters or 100.00 mL for volume) Question: What is the suitable buffer component to be used? (Note for the answer: Separate the two components with “and”; Ex: Ammonia and Ammonium chloride) Question: How much of the salt component should be used?…5. A 300.0 mg sample containing Na,CO3, NaHCO3 and NaOH and inert material either alone or in some combination was dissolved and titrated with 0.1000 M HCI the titration required 24.41 mL to reach the phenolphthalein endpoint. And an additional 8.67 mL to reach the methyl red endpoint. Determine the composition of the sample and calculate the percent of each titrated component.
- 2. In one gravimetric analysis, the aluminum in a 1.2g sample of impure NHAI(SO4)2 was precipitate as hydrous ALO3.XH2O. The precipitate was filtered and ignited at 1000 °C to give anhydrous Al2O3 which weighed 0.1798g. Calculate the % Al inthe sample. 3. A sample of 0.4500g impure potassium chloride was dissolved in water treated with excess silver nitrate solution. 0.8402 g of silver chloride was precipitated. What is the percentage of potassium chloride in the sample?Q: 1: The distribution constant for iodine between an organic solvent and H;O is 85. Find the concentration of I; remaining in the aqueous layer after extraction of 50.0ml. of 1.00 x 103 M I; with the following quantities of the organic solvent: (a) 50.0 ml.; (b) two 25.0 ml. portions; (c) five 10.0 ml. portions. Q: 2: An acidic solute, HA, has an acid dissociation constant of 1.00 x10, and a partition coefficient between water and benzene of 3.00. Calculate the extraction efficiency when 50.00 mL of a 0.025 M aqueous solution of HA buffered to a pH of 3.00, is extracted with 50.00 mL of benzene. Repeat for cases in which the pH of the aqucous solution is buffered to 5.00 and 7.00.A 370.00 mL solution of 0.00190 M AB5 is added to a 200.00 mL solution of 0.00165 M CD2. What is pQsp for AD5?
- The concentration of ammonia in a cleaning product was determined by back titration.Firstly, 10.00 cm3 of the cleaning product was pipetted into a large conical flask,containing 250.00cm3 of 0.50 mol/l HCl to give Solution A.Following a period of reaction and shaking, 50.00cm3 of Solution A was removed anddiluted to 250 cm3 with water in a volumetric flask to give Solution B.20 cm3 samples of Solution B were titrated against 0.05 mol/l Na2CO3 solution, givingan average titre of 12.45 cm3. i) Write equations for the reactions that have taken place.ii) Determine the concentration of NH3 in the original cleaning product in mol/l,g/l, ppm, and % w/v.The ethyl acetate concentration in an alcoholic solution was determined by diluting a 10.00-mL sample to 100.00 mL. A 20.00-mL portion of the diluted solution was refluxed with 40.00 mL of 0.04672 M KOH:CH3COOC2H5 + OH- → CH3COO- + C2H5OHAfter cooling, the excess OH2 was back-titrated with 3.41 mL of 0.05042 M H2SO4. Calculate theamount of ethyl acetate (88.11 g/mol) in the original sample in gramsUEid- base tit ration the Consentrat ion of ammonia Solution excess HCL was titrated ith o.07om Na, cO3 Solutian. The volume of Na, Coz Solution reguired was 15.50 ml using the following eguations: 2HCLem> + Na, COgcaps CO2 Cays + HzO1) t NaCL Calculate the concentration (molarity and ppm) of ammonia in the Original Solution.(MM of NHzis 17.031.9/4) 10.0 was by of o.10OMI HCE to Then
- Q: 1: The distribution constant for iodine between an organic solvent and H,0 is 85. Find the concentration of I; remaining in the aqueous layer after extraction of 50.0ml. of 1.00 x 10 M I with the following quantities of the organic solvent: (a) 50.0 ml.; (b) two 25.0 ml. portions; (c) five 10.0 ml. portions. Q: 2: An acidic solute, HA, has an acid dissociation constant of 1.00 x10, and a partition coefficient between water and benzene of 3.00. Calculate the extraction efficiency when 50.00 ml. of a 0.025 M aqueous solution of HA buffered to a pH of 3.00, is extracted with 50.00 mL of benzene. Repeat for cases in which the pH of the aqueous solution is buffered to 5.00 and 7.00.A 10.00cm3 portion of the 100.00cm3 HCl solut was taken from the volumetric flask and was titrated with KOH (aq). It was neeutralized by 24.35cm3 of potassium hydroxide od concentration 0.0500moldm-3. Calculate the concentrat of the original concentrated hydrochloric acid in moldm-3.An unknown sample containing mixed alkali (NAOH, NaHCO3, or NazCO3) was analyzed using the double flask method. A 250 mg sample was dissolved in 250 mL CO, free water. A 20.0 mL aliquot of this sample required 11.3 mL of 0.009125 M HCI solution to reach the phenolphthalein end point. Another 29.0 mL aliquot of the sample was titrated to the bromocresol green endpoint using 311 mL of the standard acid. What is/are the component/s of the sample? O Cannot be determined O NAHCO3 only O NAOH and Na,CO3 O NazCO3 only O NAHCO, and Na2CO3