(a) Explain the following observations: (1) (ii) (iii) For a given metal ion, the thermodynamic stability of polydentate ligand is greater than that of a complex containing a corresponding number of comparable monodentate ligands. The K, value for [Cu(NH3)4] and [Cu(en)₂]²* is 1.1 x 10¹3 and 1.0 x 1020, respectively. The compound Pt(CO), is known but cluster (CO)3Pt(μ-Cl)₂Pt(CO) has never been prepared.
(a) Explain the following observations: (1) (ii) (iii) For a given metal ion, the thermodynamic stability of polydentate ligand is greater than that of a complex containing a corresponding number of comparable monodentate ligands. The K, value for [Cu(NH3)4] and [Cu(en)₂]²* is 1.1 x 10¹3 and 1.0 x 1020, respectively. The compound Pt(CO), is known but cluster (CO)3Pt(μ-Cl)₂Pt(CO) has never been prepared.
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 11QRT
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Question
![(a)
Explain the following observations:
(1)
(ii)
(iii)
For a given metal ion, the thermodynamic stability of polydentate ligand
is greater than that of a complex containing a corresponding number of
comparable monodentate ligands.
The K, value for [Cu(NH3)4]2+ and [Cu(en)₂]²* is 1.1 x 10¹3 and 1.0 x 102⁰,
respectively.
The compound Pt(CO), is known but cluster (CO)3Pt(μ-Cl)₂Pt(CO) has
never been prepared.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fee246e18-2686-4f3b-bfb2-23125dafcffa%2Ffa2950ba-1bb7-4ac4-96a6-516c7c822d24%2Fp3fdnze_processed.jpeg&w=3840&q=75)
Transcribed Image Text:(a)
Explain the following observations:
(1)
(ii)
(iii)
For a given metal ion, the thermodynamic stability of polydentate ligand
is greater than that of a complex containing a corresponding number of
comparable monodentate ligands.
The K, value for [Cu(NH3)4]2+ and [Cu(en)₂]²* is 1.1 x 10¹3 and 1.0 x 102⁰,
respectively.
The compound Pt(CO), is known but cluster (CO)3Pt(μ-Cl)₂Pt(CO) has
never been prepared.
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