A quantitative analysis for ethanol, C2H60, is accomplished by a redox back titration. Ethanol is oxidized to acetic acid, C2H40O2, using excess dichromate, Cr207 2- ', which is reduced to Crt. The excess dichromate is titrated with Fe2*, giving Cr* and Fe3+ as products. In a typical analysis, a 5.00-mL sample of a brandy is diluted to 500 mL in a volumetric flask. A 10.00-mL sample is taken and the ethanol is removed by distillation and collected in 50.00 mL of an 2- acidified solution of 0.0200 M K2Cr207. Titration of the unreacted Cr207 requires 21.48 mL of 0.1014 M Fe2+. Calculate the %w/v ethanol in the brandy. Which is the analyte in this problem? O C2H60 O cr207 2- O C2H402 O Fe2+

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter4: Reactions In Aqueous Solution
Section: Chapter Questions
Problem 77QAP: A 300.0-g sample of a solid is made up of a uniform mixture of NaNO3, MgCl2, and BaCl2. A 100.0-g...
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A quantitative analysis for ethanol, C2H60, is accomplished by a redox back titration. Ethanol is oxidized to acetic acid, C2H402, using excess dichromate,
2-
Cr207, which is reduced to Cr3*. The excess dichromate is titrated with Fe2+,
of a brandy is diluted to 500 mL in a volumetric flask. A 10.00-mL sample is taken and the ethanol is removed by distillation and collected in 50.00 mL of an
giving
Cr3+
as products. Ina typical analysis, a 5.00-mL sample
and Fe3+
acidified solution of 0.0200 M K2Cr207. Titration of the unreacted Cr207 requires 21.48 mL of 0.1014 M Fe2*. Calculate the %w/v ethanol in the brandy.
2-
Which is the analyte in this problem?
C2H60
O Cr207 2-
C2H402
Fe2+
Transcribed Image Text:A quantitative analysis for ethanol, C2H60, is accomplished by a redox back titration. Ethanol is oxidized to acetic acid, C2H402, using excess dichromate, 2- Cr207, which is reduced to Cr3*. The excess dichromate is titrated with Fe2+, of a brandy is diluted to 500 mL in a volumetric flask. A 10.00-mL sample is taken and the ethanol is removed by distillation and collected in 50.00 mL of an giving Cr3+ as products. Ina typical analysis, a 5.00-mL sample and Fe3+ acidified solution of 0.0200 M K2Cr207. Titration of the unreacted Cr207 requires 21.48 mL of 0.1014 M Fe2*. Calculate the %w/v ethanol in the brandy. 2- Which is the analyte in this problem? C2H60 O Cr207 2- C2H402 Fe2+
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