A typical vibrational frequency for a cabonyl is 1600-1900 cm³¹. For carbon monoxide, e is approximately 2180 cm Which of the following is a reasonable explanation for why is larger for CO than for R'-C(=O)-R. O The force constant for CEO is larger than that for C-O due to the larger bond multiplicity. O The reduced mass for C=O is larger than that for C-O due to the larger bond multiplicity. O The force constant for C=O is smaller than that for C-O due to the larger bond multiplicity. O The reduced mass for C=O is smaller than that for C-O due to the larger bond multiplicity.

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter14: Rotational And Vibrational Spectroscopy
Section: Chapter Questions
Problem 14.60E
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A typical vibrational frequency for a cabonyl is 1600-1900 cm ¹. For carbon monoxide, is approximately 2180 cm ¹.
Which of the following is a reasonable explanation for why is larger for CO than for R'-C(=O)-R.
O The force constant for C=O is larger than that for C-O due to the larger bond multiplicity.
The reduced mass for C=O is larger than that for C-O due to the larger bond multiplicity.
The force constant for C=O is smaller than that for C-O due to the larger bond multiplicity.
The reduced mass for C=O is smaller than that for C-O due to the larger bond multiplicity.
Transcribed Image Text:A typical vibrational frequency for a cabonyl is 1600-1900 cm ¹. For carbon monoxide, is approximately 2180 cm ¹. Which of the following is a reasonable explanation for why is larger for CO than for R'-C(=O)-R. O The force constant for C=O is larger than that for C-O due to the larger bond multiplicity. The reduced mass for C=O is larger than that for C-O due to the larger bond multiplicity. The force constant for C=O is smaller than that for C-O due to the larger bond multiplicity. The reduced mass for C=O is smaller than that for C-O due to the larger bond multiplicity.
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ISBN:
9781133958437
Author:
Ball, David W. (david Warren), BAER, Tomas
Publisher:
Wadsworth Cengage Learning,