A. Put the following complexes in decreasing order of reactions rates under a dissociation reaction: [CuCl6]-5, [VCI6]-3 and [CoCl6]4. Justify. B. Which complexes is more labile, [Mn(H2O)6]2+ or [Mn(NC)6]4- and why? C. How does the chelate effect affects the rate of a reaction?
A. Put the following complexes in decreasing order of reactions rates under a dissociation reaction: [CuCl6]-5, [VCI6]-3 and [CoCl6]4. Justify. B. Which complexes is more labile, [Mn(H2O)6]2+ or [Mn(NC)6]4- and why? C. How does the chelate effect affects the rate of a reaction?
Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter22: The Chemistry Of The Transistion Elements
Section: Chapter Questions
Problem 69SCQ
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![A. Put the following complexes in decreasing order of
reactions rates under a dissociation reaction:
[CuCl6]-5, [VCI6]-3 and [CoCl6]4. Justify.
B. Which complexes is more labile, [Mn(H2O)6]2+ or
[Mn(NC)6]4- and why?
C. How does the chelate effect affects the rate of a
reaction?
D. An
the electron transfer mediated through a bridging
ligand. Marcus Theory was developed as to provide
evidence for
mechanisms in electron transfer reactions. The Frank-
Condon principle is used to explain the mechanism of
(inner, outer) sphere mechanism involves
(inner, outer) sphere
an
(inner, outer) sphere reaction.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F2c4f8981-e3da-46b6-8036-92ba4b3247c9%2Fac86bd7b-4277-431e-b24f-3218a457193e%2F5aq6sc9_processed.jpeg&w=3840&q=75)
Transcribed Image Text:A. Put the following complexes in decreasing order of
reactions rates under a dissociation reaction:
[CuCl6]-5, [VCI6]-3 and [CoCl6]4. Justify.
B. Which complexes is more labile, [Mn(H2O)6]2+ or
[Mn(NC)6]4- and why?
C. How does the chelate effect affects the rate of a
reaction?
D. An
the electron transfer mediated through a bridging
ligand. Marcus Theory was developed as to provide
evidence for
mechanisms in electron transfer reactions. The Frank-
Condon principle is used to explain the mechanism of
(inner, outer) sphere mechanism involves
(inner, outer) sphere
an
(inner, outer) sphere reaction.
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