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- The activation energy for the gas phase decomposition of acetic anhydride is 144 kJ. (CH3CO)2O → CH₂=C=O + CH3COOH S The rate constant at 493 K is 5.48 x 10-4 s-1. The rate constant will be 0.00745s¹ at K.(1) The activation energy for the gas phase isomerization of methyl cis-cinnamate is 174 kJ.cis-C6H5CH=CHCOOCH3trans-C6H5CH=CHCOOCH3The rate constant at 621 K is 8.10×10-5 /s. The rate constant will be 8.42×10-4 /s at_____ K. (1b) The activation energy for the gas phase isomerization of methyl cis-cinnamate is 174 kJ.cis-C6H5CH=CHCOOCH3trans-C6H5CH=CHCOOCH3The rate constant at 654 K is 4.57×10-4 /s. The rate constant will be /s at _______ 695 K.Calculate the velocity of the reaction (M · s–1) of an α-amino group in a blood protein at 37°C if its concentration is 0.60 mM and the partial pressure of carbon dioxide is 40 torr. Use 2 significant figures and scientific notation (example: 1000 would be entered as 1.0e+3). The rate constant k for this reaction is 4950 M–1·s–1.
- Methyl acetate (CH;COOCH3) is formed by the reaction of acetic acid with methyl alcohol. If the methyl alcohol is labeled with oxygen-18, the oxygen-18 ends up in the methyl acetate: CH;COH + HSOCH3 CH;Č18OCH3 + H,O (a) Do the C-OH bond of the acid and the O-H bond of the alcohol break in the reaction, or do the O-H bond of the acid and the C-OH bond of the alcohol break? (b) Imagine a similar experiment using the radioisotope H, which is called tritium and is usually denoted T. Would the reaction between CH;COOH and TOCH; provide the same information about which bond is broken as does the above experiment with Hl$OCH;?но HO HO HO 0 + ½ O, → + H,0 H H но он ascorbic acid dehydroascorbic acid Vitamin C is oxidized slowly to dehydroascorbic acid by the oxygen in air. It is catalyzed by ions such as Cu*2 and Fe*3. The reaction can be followed by measuring the ultraviolet absorbance at 243 nm. Time (hours) Absorbance (A) 1/A In A - In A 0.75 1.3 -0.29 0.29 1 0,38 2.6 -0.97 0.97 2 0.19 5.3 - 1.7 1.7 3 0.095 11 - 2.4 2.4 28. A new compound is synthesized and found to be a monoprotic acid with a molar mass of 248 g/mole. When 0.0050 moles of this acid are dissolved in 0.500L of water, the pH is measured as 2.94. What is the pKa of this acid? (A) (B) (C) (D) 2.33 3.89 5.78 7.78 29. What is the hybridization of carbon 1 (far left) and carbon 2 (middle) in this hydrocarbon: CH3CH=CH2? (A) sp³, sp (B) sp?, sp? (C) sp³, sp? (D) sp, sp?Activated complex 200 (a) 150 Potential Reactants (b) Energy 100 (c) Products 50 Reaction Pathway Nina claims that the graph shown above represents an exothermic reaction with a AH of +100kJ and that energy will be absorbed during this reaction. Is Nina correct? If not, explain and correct her mistake giving explanation. Format BIU- a Farch
- The data below was collected from three trials of the following reaction: 2ClO2 (aq) + 2OH- (aq) --> ClO3- (aq) + ClO2- (g) + H2O (l) [ClO2]o (M) [OH-]o (M) Initial Rate (M/s) 1 0.0500 0.100 5.75 x 10-2 2 0.100 0.100 2.30 x 10-1 3 0.100 0.0500 1.15 x 10-1 If the initial concentrations were as follows, [ClO2]o= 0.25 M and [OH- ]o = 0.095 M, what would the initial rate be?The data below was collected from three trials of the following reaction: 2ClO2 (aq) + 2OH- (aq) --> ClO3- (aq) + ClO2- (g) + H2O (l) [ClO2]o (M) [OH-]o (M) Initial Rate (M/s) 1 0.0500 0.100 5.75 x 10-2 2 0.100 0.100 2.30 x 10-1 3 0.100 0.0500 1.15 x 10-1 a) What is the generic rate law for this reaction? b) What is the order for each reactant? What is the order for the overall reaction? c) What is the complete rate law for this reaction? d) If the initial concentrations were as follows, [ClO2]o = 0.25 M and [OH- ]o = 0.095 M, what would the initial rate be?Given the reaction 2Fe2+ + O3 + 5H2O -> 2Fe(OH)3 + O2 + 4H+, estimate the loss rate of Fe2+ and production rate of O2 when the rate of loss of O3 is 0.1 μmol/L·min.
- Under dissolving indium chloride (InCℓ) in hydrochloric acid (HCℓ), In+ (aq) undergoes disproportionation reaction according to the following unbalanced equation. In+ (aq) = In (s) + In3+ (aq) This disproportionation follows a first – order kinetics with a half-life of 667 s.(a) What is the concentration of In+(aq) after 1.25 hours if the initial solution of In+ (aq) was prepared by dissolving 2.38 g InCℓ (s) in 5.00 x 102 mL of dilute hydrochloric acid?(b) What mass of In (s) is formed after 1.25 hours? (c) Determine the rate constant k, for this reaction. (d) Sketch a graph of [In+] versus time (sec) over a period of 3 hours.ΚΗ Consider the following reaction which has the observed kinetic isotope effect = 1.5. kD Cy2 "PH Δ Cy2 -PI...pt + -P Cy2 Cy2 A) Draw a mechanism for this reaction and identify the type of reaction which is occurring.Referring to the attached information, select the TRUE statements: (I) The bromide ion acts as a catalyst. (II) The steady state approximation can be applied to the bromide ion. (III) It is a heterogeneous catalysis. (IV) The maximum point of the graph in the reaction energy profile corresponds to the slow stage. (V) The reaction is catalyzed by the protonated cation of nitrous acid. (VI) All direct reactions are elementary and of order two.