an...rimetry Homework Home Garamond 12 Insert Draw Layout Review BIU U aA - - View V A E E Heat and Calorimetry Homework References C D 8 с 39 - = = 1.) A sample of lead pellets with a mass of 26.47 g that has an initial temperature of 89.98 °C was placed into a calorimeter containing 100.0 g of water. The temperature of the water then rose from 22.50 °C to 23.17 °C. What is the specific heat of the lead? ill

an...rimetry Homework Home Garamond 12 Insert Draw Layout Review BIU U aA - - View V A E E Heat and Calorimetry Homework References C D 8 с 39 - = = 1.) A sample of lead pellets with a mass of 26.47 g that has an initial temperature of 89.98 °C was placed into a calorimeter containing 100.0 g of water. The temperature of the water then rose from 22.50 °C to 23.17 °C. What is the specific heat of the lead? ill

Chemistry by OpenStax (2015-05-04)

1st Edition

ISBN:9781938168390

Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser

Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser

Chapter5: Thermochemistry

Section: Chapter Questions

Problem 31E: When a 0.740-g sample of trinitrotoluene (TNT), C7H5N2O6, is burned in a bomb calorimeter, the...

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A sample of nickel is heated to 99.8C and placed in a coffee-cup calorimeter containing 150.0 g water at 23.5C. After the metal cools, the final temperature of metal and water mixture is 25.0C. If the specific heat capacity of nickel is 0.444 J/C g, what mass of nickel was originally heated? Assume no heat loss to the surroundings.
Combustion of table sugar produces CO2(g) and H2O( l). When 1.46 g table sugar is combusted in a constant-volume (bomb) calorimeter, 24.00 kJ of heat is liberated. a. Assuming that table sugar is pure sucrose, C12H22O11 (s), write the balanced equation for the combustion reaction. b. Calculate E in kJ/mol C12H22O11 for the combustion reaction of sucrose.
When a 0.740-g sample of trinitrotoluene (TNT), C7H5N2O6, is burned in a bomb calorimeter, the temperature increases from 23.4 C to 26.9 C. The heat capacity of the calorimeter is 534 J/C, and it contains 675 mL of water. How much heat was produced by the combustion of the TNT sample?
9.104 An engineer is using sodium metal as a cooling agent in a design because it has useful thermal properties. Looting up the heat capacity, the engineer finds a value of 28.2 J mol-l °C-l. Carelessly, he wrote this number down without units. As a result, it was later taken as specific heat. (a) What would he the difference between these two values? (b) Would the engineer overestimate the ability of sodium to remove heat from the system or underestimate it because of this error? Be sure to explain your reasoning.
A sample of 0.562 g of carbon is burned in oxygen in a bomb calorimeter, producing carbon dioxide. Assume both the reactants and products are under standard state conditions, and that the heat released is directly proportional to the enthalpy of combustion of graphite. The temperature of the calorimeter increases from 26.74 C to 27.93 C. What is the heat capacity of the calorimeter and its contents?
The enthalpy change for the reaction CH4(g)+2O2(g)CO2(g)+2H2O(l) is 891 kJ for the reaction as written. a. What quantity of heat is released for each mole of water formed? b. What quantity of heat is released for each mole of oxygen reacted?
Microwave ovens convert radiation to energy. A microwave oven uses radiation with a wavelength of 12.5 cm. Assuming that all the energy from the radiation is converted to heat without loss, how many moles of photons are required to raise the temperature of a cup of water (350.0 g, specific heat =4.18J/gC) from 23.0C to 99.0C?
The overall reaction in a commercial heat pack can be represented as 4Fe(s)+3O2(g)2Fe2O3(s)H=1652KJ a. How much heat is released when 4.00 moles of iron are reacted with excess O2? b. How much heat is released when 1.00 mole of Fe2O3 is produced? c. How much heat is released when 1.00 g iron is reacted with excess O2? d. How much heat is released when 10.0 g Fe and 2.00 g O2 are reacted?
Explain how calorimetry works to calculate H or E for a reaction. Does the temperature of the calorimeter increase or decrease for an endothermic reaction? For an exothermic reaction? Explain.
Ammonium nitrate is an oxidizing agent and can give rise to explosive mixtures. A mixture of 2.00 mol of powdered aluminum and 3.00 mol of ammonium nitrate crystals reacts exothermically yielding nitrogen gas, water vapor, and aluminum oxide. How many grams of the mixture are required to provide 245 kJ of heat? See Appendix C for data.
9.103 One reason why the energy density of a fuel is important is that to move a vehicle one must also move its unburned fuel. Octane is a major component of gasoline. It burns according to the reaction 2C8H18(l)+25O2(g)16CO2(g)+18H2O(g) H = 1.10104 kJ Starting from this thermochemical equation, describe how you would determine the energy density, in kJ/g, for octane. Be sure to indicate what you would need to calculate or look up to complete this problem.