Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 115QRT
Related questions
Question
![4.
Sl. No.
(i)
(ii)
(iii)
(iv)
(v)
Reaction
[Co(NH3)6]³+ + [Cr(bpy)3]²+
[CO(NH3)5(OH₂)]³+ + [Cr(bpy)]²+
[Ru(phen)3]2+ + [Ru(phen)3]³+
[Ru(OH₂)6]2+ + [Ru(OH₂)6]³+
[Co(OH₂)6]2+ + [Co(OH₂)6]³+
Rate (in M-¹s-¹)
6.9 x 10²
x 104
5
≥ 10²
8.2 x 10²
5.0
With reference to the above-mentioned table, rationalize the trends in the rate of electron transfer
reactions in the following cases:
(a) i versus ii
(b) iii versus iv
(c) iv versus v](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fdf49f9df-2f68-44c7-85c3-ad55f3b3237f%2Fb01a6080-301d-401c-9988-c8519560a805%2F4dyxsl8_processed.jpeg&w=3840&q=75)
Transcribed Image Text:4.
Sl. No.
(i)
(ii)
(iii)
(iv)
(v)
Reaction
[Co(NH3)6]³+ + [Cr(bpy)3]²+
[CO(NH3)5(OH₂)]³+ + [Cr(bpy)]²+
[Ru(phen)3]2+ + [Ru(phen)3]³+
[Ru(OH₂)6]2+ + [Ru(OH₂)6]³+
[Co(OH₂)6]2+ + [Co(OH₂)6]³+
Rate (in M-¹s-¹)
6.9 x 10²
x 104
5
≥ 10²
8.2 x 10²
5.0
With reference to the above-mentioned table, rationalize the trends in the rate of electron transfer
reactions in the following cases:
(a) i versus ii
(b) iii versus iv
(c) iv versus v
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