Below, depicts the electron flow process for the synthetic schemes. This should include theprediction of significant and by-products through electronic and structural impacts. The mechanismfor pushing the arrow must be shown.SYNTHESIS OF TEREPHTALIC ACIDAICI3HCICH3CI++tolueneScheme 1. Formation of Toluene using Friedel Craft AlkylationBr2FeBr3BrBrtolueneo-Bromotoluenep-BromotolueneScheme 2. Bromination of Toluene using Br2/FeBr3ofMgC:Br`MgBretherp-Bromotoluenephenylmagnesium bromideacetic acidScheme 3. Bromo 1 methyl benzene forms Grignard reagent upon reactingmagnesiumKMN04HOHO.HOacetic acidTerephthalic acidScheme 4. Bromo 1 methyl benzoic acid undergo oxidation in presence of potassiumpermanganate to form COOH and we get the desired acid (Terephthalic acid)

Answered: Below, depicts the electron flow…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter15: Radical Reactions

Section: Chapter Questions

Problem 11E

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Complete the roadmap below by providing the correct reagents for each conversion from the list. B. C. D. G H. J. H 1. PCC in pyridine 2. ethanol with catalytic sulfuric acid 3. NBS, hv 4. LDA with propanal 1. PPh3, DMF 5. 2. nbuli 3. 2-propanone 6. NaOH 7. H₂Cr₂07 8. methylpropanoate, NaOCH3 in methanol 9. CH₂CH₂MgBr then aqueous H₂SO4 10. mCPBA
The reaction of benzene with (CH);CCH;CI in the presence of anhydrous aluminum dilanide produces principally which of these? II II IV 01 ON
1pentanol + NaBr/H2SO4 -> 1-bromopentane Limiting reagent: 1-Pentanol Percent Yield: 64.5% The typical yield for this reaction is about 80%. Compare this to the yield attained..What issues might account for the yield being lower than expected?
(b) acid, HNO3 to produce compound L. The reaction of compound L with bromine, Br2 in the presence of iron tribromide, FeBr3 produced compound M. Benzene also undergoes Fridel-crafts alkylation reaction with chloroethane, CH;CH2CI using catalyst N to produce compound P. Benzene, CeHe undergoes substitution reaction with concentrated nitric Benzena, CsHe menjalani tindak balas penukargantian dengan asid nitrik, HNO, pekat untuk menghasilkan sebatian L. Tindak balas sebatian L dengan bromin, Brz dengan kehadiran ferum tribromida, FeBrs menghasilkan sebatian M. Benzena juga menjalani tindak balas alkilasi Fridel-crafts dengan kloroetana, CH3CH2CI dengan menggunakan pemangkin N untuk menghasilkan sebatian P. (i) Draw the structural formula of L, M and P. Lukiskan formula struktur bagi sebatian L, M dan P. (ii) State catalyst N. Nyatakan pemangkin N. (iii) Show the formation of electrophile that will be reacted with benzene for the formation of compound P.
Synthesize the following compound from cyclohexanone and any other organic compound and provided reagents. 1) (CH3); CuLi (1) Br2, CH300H (1) CH3B1 C. A. В. (2) H20 (2) Li¿CO2, LiBr, DMF (2) H20 heat NaOEt, E1OH D. OH, H20 E. (1) CH3CI, DMF F. CH2(CN)2 (2) H30" Part 1 out of 3 edit structure .. Organic compound
(a) For the reaction of 1-methoxy-4-methylbenzene with CH3C(O)CI in the presence of AICI3, describe the bonding and electron distribution in 1-methoxy- 4-methylbenzene, formation and structure of the electrophile in the reaction, and the most stable intermediate responsible for the end product. i H3C1 CI, AICI 3 Me- -OMe 1-methoxy-4-methylbenzene (b) Use phenol as the substrate, propose a synthetic scheme to produce 2-allyl-4-bromophenol (Mechanism not required). Br OH OH phenol 2-allyl-4-bromophenol (c) Propose a synthesis of Compound A starting from benzaldehyde and other necessary reagents of your choice (Mechanism not required). OH CHO CI. Compound A benzaldehyde (d) For the given 13C NMR chemical shifts of the carbonyl carbons in the order of ketones > aldehydes > carboxylic acids, provide an explanation. O CH3 H3C. 13C NMR Chemical Shifts: H₂C1 H₂C H > OH 200 ppm 181 ppm 209 ppm
divls depends oin the moisture content of the reaction mixture. Propose a detailed mechanism for ench of the following steps to account for the observed The outeome of oxidation of alkenes with 1odine and silver acetate to afford stereochemistry of the product HO () 2, 2 RCO2Ag (i1) NaOH (aq) HO HO () 2, RCO2Ag, H20 (11) NaOH (aq) HO
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Which of the following best describes a key step in the mechanism for the reaction below? HO, ... -CH3 -CH3 + en dihydroxylation H3C- H3C- OH (A) free-radical substitution at the carbonyl carbon B elimination reaction by abstraction of a beta-hydrogen nucleophilic attack by an alkene to form a cyclic (epoxide) intermediate electrophilic addition reaction to form a carbocation intermediate

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Below, depicts the electron flow process for the synthetic schemes. This should include the prediction of significant and by-products through electronic and structural impacts. The mechanism for pushing the arrow must be shown.