Br. 3. Br. Classify steps I, II, and III as substitution, elimination, or addition reactions (J. Org. Chem., 2011, 76, 3968) N ا CH3 CH3 N-CH3 I سم CH3 KOH ممن ليس مالي I KOH II OH CH3 CH3 CH; CH 3 III .OH CH; CH3
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- What is(are) the major Organic product(s) in the following reaction? CH; CH; H₂C-C-0-CBr; CBr; CH; H₂C-C-0-CH; CH; CB13 Br3C C 0-CH₂ HBr (SNI) HC CH; H₂C-C-0-H CH, (b) CH; CH; Br CH;Br CH₂OH H;C CH, H₂C C | CH; CH; C CH; (c) H CH + CH₂Br CH; 0—C—CH; -CH:OCH:Electron pairs CH3 .. Erase H3C - С — СІ: H3C – S- CH3 CH3 CH, CH3 THF/H,0 + H,C--CH, CH C- CH CHs CH, Use curved arrows to write the first step of this nucleophilic substitution mechanism. :ö: | :ö:Which type of reaction – addition, elimination, rearrangement, substitution,- best describes each of the following? OLi (а) MeLi + Me H (Б) Me2NOH + (c) to (d) H2O -ОН +
- Identify the major product of this reaction of an alkene. | ||| OH OH 1. Hg(OAc)2, H2O 2. NaBH4, NaOH || IV ㅊ OH OHa. + CH3MGBRDetermine whether each pair of structures are isomers or the same molecule drawn in two different ways. a. CH;-CH2-C-o-CH, CH;-C-o-CH2-CH; b. с. СH, — НС —сH—CH, CH;CH, CH; CH,-HC-CH-CH, CH3
- Provide structures of the reactant/products: 1. MgBr 1. KCN a) 2. Нзо" 2. H30* 1. CH;ONa 1. NABH4 2. H30* 2. H30* 6) COOt Na OEt .cOOEt H20* 1. NaOCH2CH3 2. НаоOrder the following in increasing priority A. -C, -CH, -OL B. -CH3, -CH2OH, -CH2CH3 C. -C≡CH, -CH゠CH2, -CH゠O3. Which carbon would the Br of HBr add to in the following unsymmetrical alkenes? 1 Problem Set #7 Chemistry 227 а. b. С. d. H3C H3C е. H Н. H3C. TH. CH3 H H H the C=C in the ring do not react with H*
- In an associative substitution reaction а. AS# > 0 b. AS# 0Each H↔H eclipsing interaction in ethane costs about 4.0 kJ/mol. How many such interactions are percent in cyclopropane? What fraction of the overall 115 kJ/mol (27.5 kcal/mol) strain energy of cyclopropane is due to torsional strain.Q2. Provide the reagents O OMe OMe CO₂Me CO₂Me