Answered: Calculate the potentials after the…

Calculate the potentials after the addition of 10.00, 25.00, 49.00, 50.00, 50.10, 60.00 mL of the reagent for the titration of 50.00 mL of 0.1000 M Fe(CN)6+ with 0.0500 M TI³+.

Chemistry & Chemical Reactivity

10th Edition

ISBN:9781337399074

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter17: Principles Of Chemical Reactivity: Other Aspects Of Aqueous Equilibria

Section17.6: Equilibria Involving Complex Ions

Problem 1.2ACP: What is the minimum volume of 0.0071 M NaCN(aq) necessary to dissolve the gold from 1.0 metric ton...

See similar textbooks

Related questions

Q: 8. Circle the descriptor that most accurately characterizes the relationship between the two…

A: Diastereomers are the non mirror images of each other. Enantiomers are the super imposable mirror…

Q: 1. Provide a systematic name (assigning absolute stereochemistry if necessary) for each of the…

A: We are authorised to solve first three subparts of a question. Please post rest of the subparts…

Q: What round of beta oxidation can the intermediate 3, 5, 8 dienoyl CoA be generated from linoleic…

A: The molecular formula of linoleic acid is: C18H32O2. Each round of beta oxidation produces one…

Q: Pretend you are a teacher or tutor helping a group of students understand molecular structure. They…

Q: 1. Rank the following from lowest to highest entropy. (a) CaH:s (1), CaHso(g), CaoHs (5) (b) Si (s),…

A: The correct answer about entropy is given below

Q: Calculate the mass of sodium-24 that will remain in a 20.0 g sample after 75 hours. Sodium has a…

A: Chemical kinetics is branch of chemistry in which we deal with the speed at which rate of reaction…

Q: Ni(CO).(g) ← 2 03(g) → 3 O₂(g) Ni(s) + 4 CO(g)

A: Write the expression for Kc (equilibrium constant) for the following reactions.

Q: Q3: Explain the reasons why the energy of an absorbed photon is not equal to the energy of the…

A: Fluroscene is a type of photolumiesence when a Molecule is excited by uv light or visible light.

Q: 1. What is the nucleophile in the reaction? 2. The reaction above follows what mechanism? 3. What is…

A: It is the basic part of the reaction mechanism. Here we have to be clear about the nucleophile,…

Q: Calculate the wt of oxalic acid required to prepare 1,000mL of 0.2 N of the solution.

A: Given, The mass of oxalic acid required to prepare 1000mL of 0.2 N of the oxalic acid solution is:

Q: 17. When aluminum reacts with hydrochloric acid, the predicted products would be (you do not n to…

A: Dear student, since the given question is a multiple question ,hence I solved first three question .

Q: Compound A Compound B Differentiating Chemical test (1) (3) Positive sign/s of reaction formation of…

A: To fill in the appropriate information needed to distinguish the following compounds given

Q: Synthesize B from A keeping stereochemistry in mind: N 111 A у ome HC

A: In this question, we will synthesized B from starting material A and also keeping stereochemistry in…

Q: To what do you attribute the deactivating nature of halides in electrophilic aromatic substitution?…

A: Halogens are deactivating groups which decreases the rate of electrophilic aromatic substitution.…

Q: 2. The kinetics of an enzyme are measured as a function of substrate concentration in the presence…

A: Since you have asked multiple questions, we will solve the first question for you. If you want any…

Q: illustrate (draw) what is the corresponding structure of the given compounds. H₂C + CH3OH (+ excess…

Q: ethyl mercaptan concentration in a mixture was determined by shaking a 2.0430-g sample with 50.00 mL…

Q: 0.9000-g of KIO3 is dissolved in 500-mL distilled water. A 50.0-mL aliquot portion was run down into…

Q: A 0.4 m rod of a metal elongates 0.48 mm on heating from 20 to 100°C. Determine the value of the…

Q: Determine the first step of this mechanism.

Q: The Hydrogen isotope, tritium, is radioactive and has a half-life of 12.5 years. What percentage of…

Q: To what structural effect do you attribute the preference of methyl bromide over t-butyl bromide in…

A: Alkyl halide undergoes substitution reaction via either SN1 or SN2 pathway depending upon the…

Q: 6. Briefly identify the important differences between an alkene and an alkyne. How are they similar?…

A: Here we have to differentiate between alkene and alkyne. Also explain why alkyne do not show…

Q: SiH2F2 geometry and molecular model

Q: How long would it take to electroplate a flute with 28.3 g of silver (107.87 g/mol) at a constant…

A: Given-> Weight of Ag = 28.3 gm Atomic mass of Ag(MM) = 107.87 g/mole Current (i) = 2.0 ampere

Q: In the following reactions, for each letter below (1) predict whether the reaction will undergo…

A: Here we have to predict types of reactions and major product formed in the following reactions.

Q: Write the condensed structures corresponding to the following names. 1. 3-ethyl-5; 5-dimethylectanal…

Q: C. Draw the skeletal structure and give the IUPAC name for each compound. Condensed Structure…

Q: Determine the functional group of each letter: a. b. C. d. CH₂ d a b -CH₂ с

A: Write the functional group of the given structure---

Q: 28.5 g

A: Mass of 1 square inch of air =14.7 psi 1 psi =453.592 grams 14.7 psi= =14.7 x 453.592 =…

Q: A student prepares a 0.15M aqueous solution of butanoic acid (C3H,CO₂H). Calculate the fraction of…

A: This question is from chapter Ionic equilibrium where we are dealing with a weak acid like butanoic…

Q: Kmax = (6.63x1034 J.s) (7.09x10¹4 s¹)-(2.17x10 J) h. y = 2.25×108 m/s 3.00×108 m/s 1.

Q: Research the following 2 things about water treatment (NOT WASTEWATER). For each, provide the URL of…

A: Water treatment is done to improve the quality of water.After treatment water is used for various…

Q: ОН О-С-ОН O=C-C 0=C-0 ОН Br NO₂ H2C-CH3 ОН IV V Ш I 11 . Rank the following acids by acid strength,…

A: Given-> Strength of acid can be determined by stability of conjugate base if conjugate base is…

Q: What is the oxidation number of Na in Na2SO4 What is the oxidation number of H in CaH2 What is the…

A: Here we are required to find the oxidation number of each species

Q: 2. The reaction of between hydrazine (N₂H₁) and dinitrogen tetroxide (N₂0₂) in their liquid form is…

Q: One carat is equivalent to a mass of 0.200 g. Use the fact that 1 kg (1000 g) has a weight of 2.205…

A: Given, The weight of a diamond is 1414 carat. The weight of a diamond in pounds is:

Q: What is the specific heat of an unknown matter if a 20.00 kg of it released 300000.0 J of heat to…

Q: 14.107 Consider the reaction that takes place in a lead-acid battery when it discharges: Pb (s) +…

A: Option (A), (B) and (C) are incorrect. Oxidation state of Pb(s) increases from 0 to +2. So it…

Q: is A a nitrile or nitro? is B ester or carboxylate or carbonyl?

A: A is neither nitro nor nitrile ,, A is amine B is Carbonyl group

Q: Five white, 500-mg uncoated ascorbic acid (AA) tablets with an average weight of 0.6152-g were…

Q: 1. A solution is prepared by dissolving 4.00 g of NaOH in 100.00 g of water. The volume of the…

A: Given: Mass of NaOH = 4.00 g Mass of water = 100.00 g Volume of solution = 102.00 mL

Q: Write the expression for Kc (equilibrium constant) for the following reactions.

A: In the expression of Kc concentration of species is written and pure solid and pure liquid do not…

Q: Nitrox is a gas mixture containing additional oxygen, often used in scuba diving. A particular…

A: Given-> Oxygen by mass = 32.2 % Total pressure (P) = 1520 mmHg = 1520/760 atm P = 2 atm (1 atm =…

Q: What is the area in square centimeters of an 8.5 inch by 14 inch sheet of paper?

A: Since the length of two sides of paper is unequal so this paper is rectangular shape. We know the…

Q: 9. Explain briefly why ethers are used as solvents?

A: According to bartleby guidelines we're supposed to answer only first question among these questions…

Q: Solve the following problems. Show your solution on a separate sheet of paper. Round off all final…

Q: OH + H₂CRO4 → (a) 1. 2. H₂C=CHCH3 + H*/H₂O → (b) 3. CH3CH₂CH₂Br + LiAlH4 → (c)

Q: The Mass: The A block is :19.30kg The B block is : .40kg The C block is : 19:32kg…

A: In the above question, mass and volume of some compounds are given.

Q: The reaction between chlorocyclohexane and sodium hydroxide in the presence of ethanol at high temp.…

A: In presence of heat elimination take place.

Question

5. Calculate the potentials after the addition of 10.00, 25.00, 49.00, 50.00, 50.10,
60.00 mL of the reagent for the titration of 50.00 mL of 0.1000 M Fe(CN)6+ with
0.0500 M T1³+.
Fe(CN)6³ + e Fe(CN)6+
Eº=+0.36 V
T1³+ + 2e
Tl*
Eº=+1.25 V

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Step by step

Solved in 4 steps with 3 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

A 100.0 mL100.0 mL solution of 0.0200 M Fe3+0.0200 M Fe3+ in 1 M HClO41 M HClO4 is titrated with 0.100 M Cu+0.100 M Cu+, resulting in the formation of Fe2+Fe2+ and Cu2+Cu2+. A PtPt indicator electrode and a saturated Ag∣∣AgClAg|AgCl electrode are used to monitor the titration. Calculate the values of ? for the cell after each of the given volumes of the Cu+Cu+ titrant have been added.
A 100.0 mL100.0 mL solution of 0.0200 M Fe3+0.0200 M Fe3+ in 1 M HClO41 M HClO4 is titrated with 0.100 M Cu+0.100 M Cu+, resulting in the formation of Fe2+Fe2+ and Cu2+Cu2+. A PtPt indicator electrode and a saturated Ag∣∣AgClAg|AgCl electrode are used to monitor the titration. Write the balanced titration reaction. titration reaction: Fe3++Cu+⟶Fe2++Cu2+Fe3++Cu+⟶Fe2++Cu2+ Complete the two half‑reactions that occur at the PtPt indicator electrode. Write the half‑reactions as reductions. half‑reaction: ?∘=0.161 V half‑reaction: ?∘=0.767 V Select the two equations that can be used to determine the cell voltage at different points in the titration. ?E of the Ag∣∣AgClAg|AgClelectrode is 0.197 V.0.197 V. ?=0.767 V−0.05916×log([Cu2+][Cu+])−0.197 V E=0.767 V−0.05916×log([Cu2+][Cu+])−0.197 V ?=0.767 V−0.05916×log([Fe3+][Fe2+])−0.197 V E=0.767 V−0.05916×log([Fe3+][Fe2+])−0.197 V ?=0.767 V−0.05916×log([Cu+][Cu2+])−0.197 V E=0.767…
Calculate the potential at the equivalence point in the titration of 100 mL 0.100 M Fe²+ in 0.500 M H,SO, with 100 mL of 0.0200 M MnO4¯. Keg = 50 × 1062 E Fe3+/Fe2+=0.771V %3D
The concentration of cyanide,CN- , in a copper electroplating bath can be determined by a complexometric titration with Ag+, forming the soluble Ag(CN)2 - complex. In a typical analysis a 5.00- mL sample from an electroplating bath is transferred to a 250-mL Erlenmeyer flask, and treated with 100 mL of H2O, 5 mL of 20% w/v NaOH, and 5 mL of 10% w/v KI. The sample is titrated with 0.1012 M AgNO3, requiring 27.36 mL to reach the endpoint as signaled by the formation of a yellow precipitate of AgI. Report the concentration of cyanide as parts per million of NaCN.
49.97 mL of 0.08726 M potassium oxalate buffered at pH 8.27 is titrated with 0,07172 M potassium permanganate. What is the potential after 39.47 mL of potassium permanganate has been added? Report just the potential in volts.
A titration of 50.00 mL of 0.1100 M Fe3+ with 0.07750 M Sn2+ is carried out. The analytical reaction is 2Fe3+ + Sn2+ ⇋ 2Fe2+ + Sn4+ and Fe3+ + e− ⇋ Fe2+ E° = +0.732 V Sn4+ + 2e− ⇋ Sn2+ E° = +0.139 V What is the potential after 8.00 mL of Sn2+ has been added?
A titration of 50.00 mL of 0.1100 M Fe3+ with 0.07750 M Sn2+ is carried out. The analytical reaction is 2Fe3+ + Sn2+ ⇋ 2Fe2+ + Sn4+ and Fe3+ + e− ⇋ Fe2+ E° = +0.732 V Sn4+ + 2e− ⇋ Sn2+ E° = +0.139 V What is the potential at the equivalence point?
A titration of 50.00 mL of 0.1100 M Fe3+ with 0.07750 M Sn2+ is carried out. The analytical reaction is 2Fe3+ + Sn2+ ⇋ 2Fe2+ + Sn4+ and Fe3+ + e− ⇋ Fe2+ E° = +0.732 V Sn4+ + 2e− ⇋ Sn2+ E° = +0.139 V What is the volume of Sn2+ is added at the equivalence point?
Calculate the potential of the solution in the titration of 50.0 mL 0.100 M Fe2+ in 1.00 M HClO4 with 0.0167 M Cr2O72- at 10.00 mL titrant added.
For the titration of 25.0 mL of 0.0100M Sn2+ by 0.0500 M Ti3+ Calculate the potential of solution after the following volumes of Ti3+ have beed added. E0 Sn4+/Sn2+ = 0.139 V, E0 Ti3+/Ti+= 0.77V A) 2.5ml B) 5.0 ml C) 6.0mL
Calculate the equivalence point potential for the titration of 50.0 mL of 0.02 M Ce** with 33.33 mil of 0.03 M Cu-² (Ce+Cut-Ce³+ Cu2) (Assume [H₂0+1 = 1.00 M) 0.939 V 0172 V 0.159 V 1.56 V
Calculate the equilibrium concentrations of Fe3+, Fe2+, Mn2+, MnO4 in a solution prepared by mixing 20.0 mL of 0.100 M KMnO4 and 20.0 mL of 0.100 M FeSO4 at pH 0.00. EMnO/Mn²+ = 1.51 V, Efe+/Fe²+ = 0.771 V MnO + 5Fe2+ + 8H+ - Mn²+ + 5Fe³++ 4H₂O 4