-CH,CH,Br + CH;CH20 kH. -CH=CH, + Br + CH;CH,OH -CD2CH2B + CH3CH20 ko. CH;CH2OD -CD=CH2 + Br +

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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When the following reactions are carried out under the same conditions, the rate constant for the first reaction (kH) is found to be 7 times greater than the rate constant for the second reaction (kD). What does that tell you about the mechanism of the reaction? (Hint: a C- D bond is 1.2 kcal/mol stronger than a C—H bond.)

-CH,CH,Br
+ CH;CH20
kH.
-CH=CH, + Br + CH;CH,OH
-CD2CH2B
+ CH3CH20
ko.
CH;CH2OD
-CD=CH2 + Br +
Transcribed Image Text:-CH,CH,Br + CH;CH20 kH. -CH=CH, + Br + CH;CH,OH -CD2CH2B + CH3CH20 ko. CH;CH2OD -CD=CH2 + Br +
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