Chemistry 2. The following experimental data are obtained for the decomposition of nitrogen dioxide: 2 NO2(g) → 2 NO(g) + O2(g) ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ Time, s [NO2], M ln[NO2], [NO2]-1, M-1 ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ 0 10.0 x 10-3 -4.605 1.00 x 102 60 6.83 x 10-3 -4.986 1.46 x 102 120 5.18 x 10-3 -5.263 1.93 x 102 180 4.18 x 10-3 -5.477 2.39 x 102 240 3.50 x 10-3 -5.655 2.86 x 102 300 3.01 x 10-3 -5.806 3.32 x 102 ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ Plot a graph of ln[NO2] versus t and 1/[NO2] versus t. Determine the decomposition of NO2 follows a first order or second order rate law with respect to [NO2].
Chemistry 2. The following experimental data are obtained for the decomposition of nitrogen dioxide: 2 NO2(g) → 2 NO(g) + O2(g) ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ Time, s [NO2], M ln[NO2], [NO2]-1, M-1 ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ 0 10.0 x 10-3 -4.605 1.00 x 102 60 6.83 x 10-3 -4.986 1.46 x 102 120 5.18 x 10-3 -5.263 1.93 x 102 180 4.18 x 10-3 -5.477 2.39 x 102 240 3.50 x 10-3 -5.655 2.86 x 102 300 3.01 x 10-3 -5.806 3.32 x 102 ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ Plot a graph of ln[NO2] versus t and 1/[NO2] versus t. Determine the decomposition of NO2 follows a first order or second order rate law with respect to [NO2].
General, Organic, and Biological Chemistry
7th Edition
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:H. Stephen Stoker
Chapter9: Chemical Reactions
Section: Chapter Questions
Problem 9.9EP: Indicate to which of the following types of reactions each of the statements listed applies:...
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Chemistry
2. The following experimental data are obtained for the decomposition of nitrogen dioxide:
2 NO2(g) → 2 NO(g) + O2(g)
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯
Time, s [NO2], M ln[NO2], [NO2]-1, M-1
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯
0 10.0 x 10-3 -4.605 1.00 x 102
60 6.83 x 10-3 -4.986 1.46 x 102
120 5.18 x 10-3 -5.263 1.93 x 102
180 4.18 x 10-3 -5.477 2.39 x 102
240 3.50 x 10-3 -5.655 2.86 x 102
300 3.01 x 10-3 -5.806 3.32 x 102
⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯
Plot a graph of ln[NO2] versus t and 1/[NO2] versus t. Determine the decomposition of NO2 follows a first order or second order rate law with respect to [NO2].
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