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- The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?AgCOAO) Prupose everystep a reaction WmechaNsm fur Hhe above showns and intermedirte.Propose an efficient synthesis CI Br NO2
- The reaction below is a base-catalyzed aldol reaction. O || CH₂-C-H CH3-C-H Ethanal (Acetaldehyde) H I CH3-C-H Ethanal (Acetaldehyde) NaOH Draw curved arrows to show the movement of electrons in the step of the mechanism shown below. Arrow-pushing Instructions AC⇒x= :O: || :CH₂-C-H OH Bl CH3-CH—CH2-CH -CH₂-1-1 a 3-Hydroxybutanal (B-hydroxyaldehyde; formed as a racemic mixture) :0: :0: || CH3—CH—CH2-C-H A tetrahedral carbonyl addition intermediate XDraw Intermediate CH3OH₂+ protonation H H3C -0 H Q CH3OH deprotonation loss of H₂O elimination H3C :0 ÖH -CH3 Draw Intermediate CH3OH deprotonatio Please select a drawing or reag. CONUERT D-LYOSE TO A +HAWTHOAN PROSECTIO (MUST Stlow ALL STEPS): OH Ho.
- Predict the products and indicate the relative stereochemistry for the following transformations. When necessary, indicate the major product. 1. Mel (excess), THE 2. Ag20, H20 3. heat H2N Me 4. cat. Cp2La(NM@2) H2N Me 1. NaOMe, MEOH, heat Me Me Me 2. NaCN, DMF 3. NH4Cl(aq) 1. ΚΗ (2.05 equiv) 18-crown-6, THF 2. Br- Br Me OEt 3. H30*, heatwhat pair of reagants can prepare diarylakene shownCurved arrows are used to illustrate the flow of electrons. Follow the arrows and draw the intermediate and product in this reaction. Include all lone pairs. Ignore stereochemistry. Ignore inorganic byproducts. :O: H :OCH3 H OH CH3 CH3OH2+ protonation CH3OH deprotonation H3C CH3OH ОН nucleophilic addition -H Draw Intermediate Q
- 4 which of tihe porlowing compounds posbesbe a 30l ehaniao (circle all possible angwers) ? kluicn of tne f0il0wing would be tue most reactive towards a nucleophilic acyl subgtitutiíon reaction?(circle your answer) पे 9. Boes tne pollowing reaction favor the formation Of pnduct H2 NA KOEE EEOH NH Yes NO OEqual amounts Of reactants and products willexist at equilibriumDraw the products formed when each ester is treated with lithium hydroxide and water. Reaction A Select Draw Rings More CH3CH₂CH(CH3)OC=OCH(CH3)₂ LiOH H₂O |||||| HO 3 Ć H O OH Li Erase Q2Q5. Draw a pathway showing how a metabolite of the following pesticide might oxidatively couple. ( 0-CH3 .CI ČI 6. Draw a degradative pathway for the following compound when dumped into an anaerobic swamp. I O2N -COOH DII 1). PrtScn Home F9 F3 F4 F5 F6 F7 F8 24 &