Consider the solubility and boiling point of the following pair of compounds: n-butyl alcohol and diethyl ether. The boiling points for the compounds are 118 °C and 35 °C respectively. The solubility for both compounds is the same (8g/100g water). Explain this observation for (i) boiling point disparity; (ii) solubility similarity a. H-bonds form in diethyl ether; n-butyl alcohol forms H-bonds in water b. H-bonds form in n-butyl alcohol; diethyl ether forms H-bonds in water c. H-bonds in n-butyl alcohol; Both compounds form H-bonds in water d. Both compounds form H-bonds; Both compounds form H-bonds in water 2. Account for the bond angle differences between (i) H-C-H (109.5°) in methane and H-S-H (90°); H-C-H (109.5°) and H-O-H (107.5°) in water. a. The H-S-H has two lone pairs; The H-O-H has two lone pairs b. The H-S-H has no hybridization at p-orbitals; The H-O-H has two lone pairs c. The H-S-H has two lone pairs; The H-O-H has
Consider the solubility and boiling point of the following pair of compounds: n-butyl alcohol and diethyl ether. The boiling points for the compounds are 118 °C and 35 °C respectively. The solubility for both compounds is the same (8g/100g water). Explain this observation for (i) boiling point disparity; (ii) solubility similarity a. H-bonds form in diethyl ether; n-butyl alcohol forms H-bonds in water b. H-bonds form in n-butyl alcohol; diethyl ether forms H-bonds in water c. H-bonds in n-butyl alcohol; Both compounds form H-bonds in water d. Both compounds form H-bonds; Both compounds form H-bonds in water 2. Account for the bond angle differences between (i) H-C-H (109.5°) in methane and H-S-H (90°); H-C-H (109.5°) and H-O-H (107.5°) in water. a. The H-S-H has two lone pairs; The H-O-H has two lone pairs b. The H-S-H has no hybridization at p-orbitals; The H-O-H has two lone pairs c. The H-S-H has two lone pairs; The H-O-H has
Chemistry: Matter and Change
1st Edition
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Chapter21: Hydrocarbons
Section: Chapter Questions
Problem 42A
Related questions
Question
1. Consider the solubility and boiling point of the following pair of compounds: n-butyl alcohol and diethyl ether. The boiling points for the compounds are 118 °C and 35 °C respectively. The solubility for both compounds is the same (8g/100g water). Explain this observation for (i) boiling point disparity; (ii) solubility similarity
a. H-bonds form in diethyl ether; n-butyl alcohol forms H-bonds in water
b. H-bonds form in n-butyl alcohol; diethyl ether forms H-bonds in water
c. H-bonds in n-butyl alcohol; Both compounds form H-bonds in water
d. Both compounds form H-bonds; Both compounds form H-bonds in water
2. Account for the bond angle differences between (i) H-C-H (109.5°) in methane and H-S-H (90°); H-C-H (109.5°) and H-O-H (107.5°) in water.
a. The H-S-H has two lone pairs; The H-O-H has two lone pairs
b. The H-S-H has no hybridization at p-orbitals; The H-O-H has two lone pairs
c. The H-S-H has two lone pairs; The H-O-H has no hybridization at p-orbitals
d. The H-S-H has no hybridization at p-orbitals; The H-O-H has no hybridization at p-orbitals
3. What is the hybridization of the carbon atom at: CO₂, and CH₂=NH?
a. sp; sp
b. sp²; sp
c. sp; sp²
d. sp²; sp²
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 3 steps with 3 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry: Matter and Change
Chemistry
ISBN:
9780078746376
Author:
Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:
Glencoe/McGraw-Hill School Pub Co
Chemistry: Matter and Change
Chemistry
ISBN:
9780078746376
Author:
Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:
Glencoe/McGraw-Hill School Pub Co