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D[α] 20 (° mL/ dm g) | α (°) | c | l |
+10.5 | 5.2 kg/ L | 35 cm | |
– 15.75 | 2.3 g/ mL | 15 cm | |
+ 5.25 | +134.45 | 1.8 g/ mL | ___cm |
+ 63.74 | + 125.8 | 42 cm |
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- ▼ Part B 2NO3(aq) +8H(aq) + 6e 3Fe(s) + 2NO3 (aq) +8H+ (aq) 3Fe(s)→→3Fe²+ (aq) + 6e →>> 2NO(g) + 4H₂0 (1) →3Fe²+ (aq) + 2NO(g) + 4H₂O(1) IVE ΑΣΦ Calculate El using the tabulated standard electrode potentials at 25 °C. cell Express your answer in volts to three significant figures. Eeell= 1.21 SWE Submit Previous Answers Request Answer 2+ X Incorrect; Try Again; 4 attempts remaining ? V stontiol buoubtrooting the electro naUsing SCH4U/grade 12 chemistry knowledge answer the question.Consider the following data set: Sample 1 2 3 4 5 Diluted Unknown (25% dilution) Diluted Unknown (50% dilution) Undiluted Unknown Absorbance at 470 nm 0.032 0.058 0.090 0.114 0.140 0.072 0.138 0.210 Concentration 1.00 x 10-³ M 2.00 x 10-³ M 3.00 x 10-³ M 4.00 x 10-³ M 5.00 x 10-³ M 1. Using MS Excel, plot a calibration curve for samples 1 to 5 (Attach a printed copy of the graph). Determine the molar absorptivity. 2. Calculate the concentration of the diluted and undiluted unknown using the linear regression equation produced from #1. 3. Back-calculate the concentration of the undiluted unknown using the calculated concentration of the 25% and 50% diluted unknown from #2. 4. Explain any significant difference that you see between the concentration of the undiluted unknown that is back-calculated from the absorbance of the 25% and 50% diluted unknown, and the concentration that is directly calculated from the absorbance of the undiluted unknown. 77
- PHOTOSYNTHETIC PIGMENTS 1.6 0.7 Qy D 1.4 CH. 0.6 1.2 Soret 0.5 A N- 0.4 0.8 H COOCH3 0.3 0.6 phytyl bacteriochlorophyll a 0.2- 0.4 0.1 0.2 - 300 400 500 600 700 800 700 750 800 850 900 2 (nm) 2 (nm) Figure 4.7 Absorption (left) and fluorescence (right) spectra of bacteriochlorophyll a in diethyl ether. 5. Look at this figure from Blankenship's book, Molecular Mechanisms of Photosynthesis. You can see the structure for bacteriochlorophyll a, along with its absorption spectrum. a. What is the molecular shape around the labeled carbon atom? b. What is the hybridization around that same carbon? c. Based on this structure, would you expect this molecule to absorb light in the visible spectrum? Why or why not? Absorbance Fluorescence (Arbitrary units)Unknown Mixture #1 Unknown Mixture #2 Sample caffeine ibuprofen aspirin acetaminoph en Distance to solvent front 14,70 cm 14,70cm 14.70cm1u.70 cm 1나,구 cm |14.구0cm 5. 70 cm 11.90 cm I.85cm Distance Spot(s) traveled 175 cm 13.75cm 11.9 5 cm 6.4 0 cm 13,75 cm 13.75 cm 38 78 1908 .8095 Calculated R:(s) 119 ,9354 812 9 43 S .9354 9354 #1:Aspirin an d lbuprofen Components of Unknowns #2: Ace taminophen, aspirin an d ibu profen D. Additional Exercises 1. Which of the substances tested is most polar? What parts of the structure of this substance is polar? The Sul 2. Which of the substance tested is most non-polar? What parts of the structure of this substance in non-polar?If the [OH] = 5.4 x10-12, the [H*] must be 1.85 x 103 %3D True False
- RMR (kcal/day) = (9.99 x 79.5kg) + (6.25 X 182.9cm) - (4.92 x 35) + (166 x 1)- 1615.50x10-2 M in acetic acid (Ka = 1.8 x 10-5) and 5.50x10-2 M in hydrocyanic acid (Ka = 4.9 x 10-10) Express your answer to two decimal places. pH = ΜΕ ΑΣΦ ? Submit Previous Answers Request Answer6. _(6a)_ 2CUSO4. + 4NaOH » CH:COOH ±_(6b)__ + 2NA2SO4 + HzO