Data mass of copper chloride in 25.0 mL of solution, g initial mass of Zn, g mass of Zn after reaction, g 51.674 mass of Zn reacted, g filter mass of wax paper, g mass of wax paper + Cu, g after 5 min. on 51.686 Büchner funnel, g 51.684 after additional 5 min. on bench, g after another 5 min. on bench, g mass of Cu produced, g mass of Cl in copper chloride, g moles of Cu in copper chloride, mol moles of Cl in copper chloride, mol empirical formula of copper chloride 2.021 g 1.6369 0.6859 0.298 Glass dish : 50.572 0.816 0.814 0.804 Calculation: Mass of Cu: Mass of Cl: Moles of Cu: Moles of Cl: Empirical Formula:

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How to get mole of Cl in copper chloride?
Data
mass of copper chloride
in 25.0 mL of solution, g
initial mass of Zn, g
mass of Zn after
reaction, g
mass of Zn reacted, g
filter
mass of wax paper, g
0.298
mass of wax paper + Glass dish : 50.572
Cu, g
after 5 min. on
51.686Büchner funnel, g
51.684 after additional 5
min. on bench, g
51.674 after another 5 min.
on bench, g
mass of Cu produced, g
mass of Cl in copper
chloride, g
moles of Cu in copper
chloride, mol
moles of Cl in copper
chloride, mol
2.021 g
1.6369
0.6859
empirical formula of
copper chloride
0.816
0.814
0.804
Section
Calculation:
Mass of Cu:
Mass of Cl:
Chem 1083-07
Moles of Cu:
Moles of CI:
-39-
Empirical Formula:
Transcribed Image Text:Data mass of copper chloride in 25.0 mL of solution, g initial mass of Zn, g mass of Zn after reaction, g mass of Zn reacted, g filter mass of wax paper, g 0.298 mass of wax paper + Glass dish : 50.572 Cu, g after 5 min. on 51.686Büchner funnel, g 51.684 after additional 5 min. on bench, g 51.674 after another 5 min. on bench, g mass of Cu produced, g mass of Cl in copper chloride, g moles of Cu in copper chloride, mol moles of Cl in copper chloride, mol 2.021 g 1.6369 0.6859 empirical formula of copper chloride 0.816 0.814 0.804 Section Calculation: Mass of Cu: Mass of Cl: Chem 1083-07 Moles of Cu: Moles of CI: -39- Empirical Formula:
2. Obtain a flat piece of clean Zn, determine its
mass, and record it. If it is covered with
plastic, remove it before weighing. The mass
of Zn should be between 1.5 and 2.0 g.
3.
Use forceps or crucible tongs to pick up the
piece of Zn Tilt the reaction beaker to a 45-
degree angle. Release the Zn so that it slowly
slides down the side of the beaker into the
solution. Make sure that none of the solution
splashes out of the beaker.
4. Continuously scrape the surface of the Zn
piece in the reaction beaker with a clean,
glass-stirring rod, so that the freshly formed
solid Cu will not be able to adhere to the
surface of Zn.
5. Allow the reaction to continue until the blue
color has disappeared from the solution (about
10-15 min.). Then, add 5 to 10 drops of 10%
aqueous hydrochloric acid to the solution, and
thoroughly stir. This will remove very fine
particles of Cu and facilitate the filtration
process.
6. Remove the remaining Zn from the solution,
using your crucible tongs. Transfer the Zn
piece to a 50 mL beaker containing 5-7 mL of
distilled water. Scrape off any adhering Cu
and remove the cleaned Zn from the beaker.
Repeat as necessary. Return all scraped off
Cu, including water, to the reaction beaker.
Dry the remaining Zn with a paper towel or
other absorbent paper. Determine the mass of
the Zn remaining.
7. Discard this Zn in the container labeled
"Discarded Zn Residue."
8. Carefully decant into a 150 mL beaker the
supernatant liquid (the aqueous solution in
the beaker) from the solid Cu, without losing
any of the metal. Discard the supernatant
liquid in the container labeled, "Discarded Zn
Solutions."
9. Set up the vacuum filtration apparatus (Figure
5.1), if it is not already set up for you.
10. Place a circular filter paper covering all the
holes in the Büchner funnel. Moisten the filter
paper with small amount of distilled water from
a wash bottle. Some liquid should be
present in the Büchner funnel throughout
the filtration to ensure a good seal between
the filter paper and the funnel.
-36-
11. Add 10 mL of distilled water to the reaction
beaker. Transfer the water/Cu into a Büchner
funnel installed onto a vacuum flask. Wash off
the remaining Cu specks using a wash bottle
filled with distilled water until all visible traces
of Cu are transferred from the beaker into the
funnel.
Buchner funnel
stopper
taped
filter
flask
water
aspirator
Figure 5.1 Suction filtration apparatus
12. Place a large beaker in the sink under the
aspirator to prevent splattering, then turn on
the aspirator to start filtering. You may have to
press the funnel onto the filter flask to develop
good vacuum. If there are any lumps, break
them up using a stirring rod. Make sure all the
water passed through the filter paper.
13. Wash the Cu with about 10 mL of acetone 3
times. Leave the aspirator running for 5
minutes to dry the Cu completely.
14. Release the vacuum by carefully twisting the
funnel and removing it from the assembly.
Turn off the tap.
15. Transfer the Cu onto a wax paper and
determine the weight of the wax paper and Cu.
Record the mass of Cu.
16. Leave the Cu on your bench top for another 5
minutes. Determine the weight of the wax
paper and Cu again. This should be within
0.05 g of the first determination. (Step 15). If
not, repeat this step until the last two readings
agree within 0.05 g. Record the weight.
17. Discard the Cu residue in the container labeled
"Discarded Cu Residue."
Caution: Wash your hands thoroughly with
soap or detergent before leaving the laboratory.
Transcribed Image Text:2. Obtain a flat piece of clean Zn, determine its mass, and record it. If it is covered with plastic, remove it before weighing. The mass of Zn should be between 1.5 and 2.0 g. 3. Use forceps or crucible tongs to pick up the piece of Zn Tilt the reaction beaker to a 45- degree angle. Release the Zn so that it slowly slides down the side of the beaker into the solution. Make sure that none of the solution splashes out of the beaker. 4. Continuously scrape the surface of the Zn piece in the reaction beaker with a clean, glass-stirring rod, so that the freshly formed solid Cu will not be able to adhere to the surface of Zn. 5. Allow the reaction to continue until the blue color has disappeared from the solution (about 10-15 min.). Then, add 5 to 10 drops of 10% aqueous hydrochloric acid to the solution, and thoroughly stir. This will remove very fine particles of Cu and facilitate the filtration process. 6. Remove the remaining Zn from the solution, using your crucible tongs. Transfer the Zn piece to a 50 mL beaker containing 5-7 mL of distilled water. Scrape off any adhering Cu and remove the cleaned Zn from the beaker. Repeat as necessary. Return all scraped off Cu, including water, to the reaction beaker. Dry the remaining Zn with a paper towel or other absorbent paper. Determine the mass of the Zn remaining. 7. Discard this Zn in the container labeled "Discarded Zn Residue." 8. Carefully decant into a 150 mL beaker the supernatant liquid (the aqueous solution in the beaker) from the solid Cu, without losing any of the metal. Discard the supernatant liquid in the container labeled, "Discarded Zn Solutions." 9. Set up the vacuum filtration apparatus (Figure 5.1), if it is not already set up for you. 10. Place a circular filter paper covering all the holes in the Büchner funnel. Moisten the filter paper with small amount of distilled water from a wash bottle. Some liquid should be present in the Büchner funnel throughout the filtration to ensure a good seal between the filter paper and the funnel. -36- 11. Add 10 mL of distilled water to the reaction beaker. Transfer the water/Cu into a Büchner funnel installed onto a vacuum flask. Wash off the remaining Cu specks using a wash bottle filled with distilled water until all visible traces of Cu are transferred from the beaker into the funnel. Buchner funnel stopper taped filter flask water aspirator Figure 5.1 Suction filtration apparatus 12. Place a large beaker in the sink under the aspirator to prevent splattering, then turn on the aspirator to start filtering. You may have to press the funnel onto the filter flask to develop good vacuum. If there are any lumps, break them up using a stirring rod. Make sure all the water passed through the filter paper. 13. Wash the Cu with about 10 mL of acetone 3 times. Leave the aspirator running for 5 minutes to dry the Cu completely. 14. Release the vacuum by carefully twisting the funnel and removing it from the assembly. Turn off the tap. 15. Transfer the Cu onto a wax paper and determine the weight of the wax paper and Cu. Record the mass of Cu. 16. Leave the Cu on your bench top for another 5 minutes. Determine the weight of the wax paper and Cu again. This should be within 0.05 g of the first determination. (Step 15). If not, repeat this step until the last two readings agree within 0.05 g. Record the weight. 17. Discard the Cu residue in the container labeled "Discarded Cu Residue." Caution: Wash your hands thoroughly with soap or detergent before leaving the laboratory.
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