Determine the rate law based on the following data: Based on the reaction mechanism, give the rate law CH,COCI(aq) + AICI₁(aq) — CH3CO*(aq) + (fast) AICI+ (aq) CH.CO (aq) + C¬H₂(aq) - C7HsOCCH(aq) (slow) AICI+ (aq) + C₂HsOCCH₁*(aq) C₂H₂OCCH(aq) + AICI (aq) + HCl(aq) (fast)
Q: Yq0o20 qa oldialv-feloivatil Amax for the transition in ethylene is 170 nm. Is the HOMO-LUMO energy…
A: HOMO = Highly occupied molecular orbital LUMO = lowest unoccupied molecular orbital HOMO-LUMO…
Q: why would the mass percent of copper in either red or black oxide be greater than, less than, or…
A: Answer :----- If there was moisture on the test tube when the mass of the copper oxide was first…
Q: 13. Hydrogen and iodine react in a closed vessel to form hydrogen iodide. H₂(g) + 12(8) 2HI(g) At…
A: Answer :----- The correct answer is (C)The reaction, as written, barely proceeds at this…
Q: Provide the reactants that would give the following aldol condensation product. H .cfl C. A. H ဘုံ…
A: To best way to get our reactants we do retro aldol that means we will move form product side to…
Q: E OTHERMOCHEMISTRY Solving combustion thermochemistry problems Try Again Your answer is wrong. In…
A: According to the law of calorimetry heat released during the course of reaction will increase the…
Q: Knowing what to look for with respect to isotopic clusters can aid in interpreting mass spectra. How…
A: Organic compounds generally contain C,H,N,O and halogens. There are 4 organic compounds given:…
Q: When the following equation is balanced, how many water molecules are present in the reactants?…
A:
Q: Oxidation of a Secondary Alcohol: isoborneol + Clorox bleach (NaOCl) + acetic acid (CH3COOH) Propose…
A: We know mild oxidation of alcohol produces aldehyde or ketone depending upon the type of alcohol.…
Q: Consider the equilibrium: 2 CrO42- (aq) + 2 H+ (aq) Cr2O72- (aq) + H2O (l) How does the…
A: We have find out the answer.
Q: Balance the following skeleton reaction and identify the oxidizing and reducing agents: Include the…
A:
Q: но Ho 2
A: Esterification is the process of combining an organic acid (RCOOH) with an alcohol (ROH) to form an…
Q: o CI 1. PPh3 2. nBuLi 3. ? Major Organic Product
A: Given reaction is wittig olefination reaction In this reaction aldehyde and ketone are convert to…
Q: The iodide in a sample that also contained chloride was converted to iodate by treatment with an…
A: In the given set of reactions shown below, in the analysis of 1.59g of sample, 0.0538 g of barium…
Q: 1. (Aldo Rxn) |. Ph مل 2. (mixed Aldol) H H .ا licH₂ 2. Nao Et, EtoH 3. H3o, A 1. Naoft Co 2. A Eto
A: The type of reactions used to give the product of the given reactions areAldol condensation…
Q: Use an Arrhenius plot to determine the frequency factor for the reaction. Express your answer using…
A: We have to calculate the frequency factor of the reaction.
Q: What mass of AgI can be produced from a 0.512-g sample that assays 20.1% All3? Precipitates used in…
A: Giventhe mass of sample = 0.512 gThe mass of AlI3 = 0.512g×20.1/100 =…
Q: electrophilic add asap pls
A: Alkene reacts with an acid to give a carbocation. Thus, 1-methylcyclohex-1-ene reacts with hydrogen…
Q: Be sure to answer all parts. M Nitrous acid, HNO2, has a K₂ of 7.1 × 104. What are [H₂0+] = [NO₂] =…
A: In the given question we have to calculate the concentration of the following, First of all, we…
Q: Draw the final product of the reaction given below. OH 1, SOCI₂ 2. CH3NH₂ The name of the functional…
A:
Q: Give the reaction of Protection and of ketone by specific protecting group with mechanism
A: The carbonyl group of ketone can also protected by 1,2 diol inpresence of H+ converting it into…
Q: Which nucleophile will not readily react with the following compound to create a more energetically…
A: We know nucleophile are those which have more electron i.e having either -ve charge or lone pair .…
Q: Arrange the following compounds in order of decreasing acidity. I || > ||| > | O III >> || ||| > ||…
A: Acidic strength depends upon the stability of carbanion which is formed by losing the H+ Ion
Q: You may have noticed that the reaction mixture was a clear, homogeneous solution before adding 1 M…
A: The given reaction scheme is shown belowWe have to give the structure of the missing organic…
Q: Find the number of protons, electrons, and neutrons in neutral atoms of the following. (a) 16/8 O,…
A:
Q: What is the major neutral Organic product for the following reaction?
A: An alcohol reacts with phosphorus oxychloride to give an alkene. This dehydration reaction occurs…
Q: formation of M+(aq) assume all atoms used are monatomic solids in the standard state
A: Here we have to write the formation equation of M+(aq) assuming all atoms used are mono atomic…
Q: Complete the following chemical reaction by showing the structural formulas of all products The…
A: In the given question, we have to find the product formed after Esterification of butanoic acid and…
Q: Be sure to answer all parts. The reaction of peroxydisulfate ion (S₂O8²) with iodide ion (I™) is…
A:
Q: Pak (44) PPM TABLE 13.1 Approximate Values of Chemical Shifts for sever Type of prote Appiate…
A: Proton NMR spectroscopy:It is type of spectroscopy that works on the principle of nuclear magnetic…
Q: quid hexane (CH. (CH₂ (CH₂) CH3) will react with gaseous oxygen (0₂) to produce gaseous carbon…
A: A balanced chemical equation contain equal number of atoms of each elements on both sides of the…
Q: Study this chemical reaction: 4 Fe+30₂-2Fe₂O3 Then, write balanced half-reactions describing the…
A: The addition of electrons or decreases in the oxidation state is known as a reduction reaction and…
Q: Fill in the name and empirical formula of each ionic compound that could be formed from the ions in…
A: An ionic compound is formed by the electrostatic interaction between the cation and the anion. A…
Q: Fill in the name and empirical formula of each ionic compound that could be formed from the ions in…
A: An ionic compound is formed by the electrostatic interaction between the cation and the anion. A…
Q: Calculate the mass, in grams, of nickel(II) chloride needed to make the 0.100 L of a 5.00 M NiCl2…
A: This question is based on mole concept. We have to first find moles of NiCl2 required. Then we have…
Q: Fill in the name and empirical formula of each ionic compound that could be formed from the ions in…
A: Use the criss-cross method to determine the formula of the compound and use the rules to name that…
Q: لبلد م جمعه لله مان ملل + HO + H2O -OH HO. H+ NaOH C HO- HO. HO HCI ملنا HO
A: Esterification is the process of combining an organic acid (RCOOH) with an alcohol (ROH) to form an…
Q: Which is the most acidic hydrogen in the following compound? D E C -H I H O H HH CN -H A -B
A: To get acidic strength first we remove acidic hydrogen after that we compare the stability of anion…
Q: 12 (9) H₂ (g) In which direction will equilibrium shift if H2 gas is added to the system? + HI is…
A: Chemical equilibrium is a condition in a reversible reaction in which no net change in the amounts…
Q: Which would you expect to be more shielded, the carbonyl carbon of an aldehyde or a ketone? Why?
A: More shielding means higher electron density around the nucleus.
Q: v-awu.aleks.com/alekscgi/x/Isl.exe/10_u-IgNslkr7j8P3jH-IQg34RWYTxj_1SoekW…
A:
Q: Calculate the amount of heat needed to melt 97.8g of solid acetic acid (HCH3CO2) and bring it to a…
A: Given mass of acetic acid is 97.8 g.the molecular mass of acetic acid is 60.052 g/mol.The melting…
Q: Draw the mechanism using curved arrow notation for the product of the reaction between 1,3 -…
A: A Diels-Alder reaction between 1,3-butadiene and maleic anhydride.
Q: Be sure to answer all parts. What mass of cesium bromide must be added to 0.500 L of water (d = 1.00…
A:
Q: Be sure to answer all parts. What are E E 0 cell AGº 0 0 and AG of a redox reaction at 25°C for…
A: Detail mathematical calculation is shown below
Q: т OH OH
A: Organic multi-step transformation
Q: Determine the oxidation state of the metal in each of the following coordination complexes:…
A: In the given question, we have to find oxidation state of metal in each case.
Q: Please match the mactions discussed for Carboxylic Acids and Esters with the correct product or…
A: To match the product of the above reactions, the below-given types of reactions are usedThe Acetic…
Q: PLEASE ASAP Compound C8H8O2 attached. What is a reasonable structure that is consistent with this…
A: In 13C nmr each line in a C-13 NMR spectrum recognizes a carbon atom in one particular environment…
Q: Note the Myoglobin O₂ binding curve below. YO2 1.00 0.80 0.60 0.40 0.20 0.0 Myoglobin O₂ Binding…
A:
Q: Provide the product of the following reaction: A. B. HO NaOH C. D. OH O
A: Here NaOH can act as a base because acid base reactions are faster than any other electrophilic and…
Step by step
Solved in 3 steps with 2 images
- The reaction of ethyl acetate with sodium hydroxide, CH3 COOC,H; (aq) + NaOH(aq) = CH3COONA(aq) + C2H; OH(aq) is first order in CH3 COOC,H; and first order in NaOH. If the concentration of CH3 COOC2H; was increased by half and the concentration of NaOH was increased by four, by what factor would the reaction rate increase? Express your answer numerically.The second-order rate constant for the reaction CH3COOC2H5(aq) + OH-(aq)→ CH3CO2-(aq) + CH3CH2OH(aq) is 0.11 dm3 mol-1 s- 1. What is the concentration of ester after(a) 15 s, (b) 15 min when ethyl acetate is added to sodium hydroxide so that the in it ial concentrations are [NaOH] 0.055 mol dm-3 and [CH3COOC2H5] = 0.150 mol dm-3?Reaction Velocity (mm/sec) Ma no !! L [1 1 L IM 3M FO Substrate Concentration (M) 1. IN Which statement is true? KM AN ALM 4V The graph above displays the kinetic profiles of the same enzyme catalyzing two different substrates. The red curve displays the higher turnover number (kcat). The red curve displays higher affinity between substrate and enzyme. The blue curve displays competitive inhibition. The red curve displays higher cooperativity,
- First order: [A]o In———- = kt [A]t t1/2= .693/k(b) The reaction between H2O2 and lodide; H,0, + 21 + 2H*→ 2H,0 + 12 Proceeds by two parallel mechanism and led to a rate laws, k, [H,0][I] and = k, [H,0][][#*] %3D dt dt The change in observed rate constants with ionic strength for both the mechanisms is given in the following table. k (M's) 0.69 k2 (M's') Sr. no. Ionic strength (1) 19.0 0.00 0.0207 0.66 15.0 3 0.0525 0.67 12.0 4 0.0925 0.68 11.3 0.69 0.1575 0.2025 9.7 0.71 9.2 With the help of this data and corresponding plots, comment on which mechanism between these two would follow Primary salt effect more prominently. rhich tyne of complex mechanism T-jumpThe reaction (CH3)3CBr + OH- -> (CH3)3COH + Br- in a certain solvent is first order with respect to (CH3)CBr and zero roder with respect to OH-. In several experiemnts, the rate constant was determined at different temepratures. A plot of ln(k) vs. 1/T was constructed resulting in a straight line with a slope of -1.10x104 K and a y-intercept of 33.5 a. determine the activation energy b. determine the frequceny factor and rate constant at 25.0C c. determine the rate constant when the temperature drops to 15.0C
- 2) (6 poin Below law, including the value of the rate constant k, and fill in the blanks for Exp. 5 and 6. There might not be enough space here for you to show your work so feel free to attach a sheet with your work if you run out of you have incomplete data tables provided by a not so careful professor... Find the rate space. [A], in M 0.014 [B], in M 0.075 Еxp. # [C], in M 0.086 Initial Rate (M/s) 0.012 0.035 0.075 0.086 0.075 0.014 0.025 0.086 0.012 0.014 0.095 0.129 0.018 0.050 0.039 0.078 0.082 0.111 0.025 123 456nd no Consider the following mechanism. (1) CIO'(aq) + H2O(I) =HC10(aq) + OH (aq) [fast] (2) I "(aq) + HCIO(aq) →HIO(aq) + Cl "(aq) [slow] (3) OH (aq) + HIO(aq) →H2O(1) + IO*(aq) [fast] (a) What is the overall equation? (b) Identify the intermediates, if any. (c) What is the molecularity and the rate law for each step?E17B.4(a) The second- order rate constant for the reaction CH,COOCH. (aa OH (aq)CH, CO,(aq) + CH,CH2OH ( aq) is 0.11 dm mois.What is the concentration of ester (CH,COOC,H) after (i) 20 s, (ii) 15 min when ethyl ethanoate is added to aqueous sodium hydroxide so that the initial concentrations are [NaOH] 0.060 mol dm and [CH,COOC,H,] = 0.110 mol dm3? re ed -3 3 AL2R C +D ation
- Integrated Rate Laus A neachn 7A→ follow fiest Order einetics Products first s /a cons tant of I.56 XIs! 2/ of 1.56X105Virimp . (3 At23 3c 2 = KEAJC6]. Initial conc.. A and 3 ane o.4m and IM after Some time conc of c dormed to be o 3 m. Ratio of Rate of Rxn at this time with Initial ate of Reaction. dindIn a chemical reaction with activation energy E. = 20 kJ/mol, (a) how many folds the rate constant is increased when the temperature increases from 300 K to 1000 K? That is, the ratio of k(1000K)/k(300K). (b) In the presence of a catalyst, the activation energy is brought down to 10 kJ/mol, how many folds the rate constant is increased at the same temperature 300K?