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Draw step Polymerisation of methyl acrylate(monomer) using benzoyl peroxide

Chemistry: Matter and Change

1st Edition

ISBN:9780078746376

Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Publisher:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Chapter22: Substituted Hydrocarbons And Their Reactions

Section22.5: Polymers

Problem 23SSC

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Types of Polymers on the basis of Method of Preparation

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Question 4. Methylvinyl ketone (MVK) can undergo a polymerization reaction in the presence of AIBN initiator to produce a poly(methylvinyl ketone) polymer according to the scheme below. NEC H3C CH3 N=N CH3 CEN CH3 azobisisobutyronitrile (AIBN) CH3 methylvinyl ketone (MVK) heat H3C CH3 NEC X n poly(methylvinyl ketone) a) Provide the mechanism for heat-induced decomposition of the AIBN initiator to produce a reactive radical species. H3C CH3 N. NCEN CH3 CH3 heat b) Provide a mechanism for the initiation step in the MVK polymerization reaction: c) Show the mechanism for the propagation step to form an MVK oligomer with n = 3: