Answered: Draw structural formulas for the…

Draw structural formulas for the a,ß-unsaturated aldehyde or ketone and the lithium diorganocuprate (Gilman reagent) that could be used in a synthesis of the compound shown below.

Macroscale and Microscale Organic Experiments

7th Edition

ISBN:9781305577190

Author:Kenneth L. Williamson, Katherine M. Masters

Publisher:Kenneth L. Williamson, Katherine M. Masters

Chapter38: Grignard Synthesis Of Triphenylmethanol And Benzoic Acid

Section: Chapter Questions

Problem 4Q

See similar textbooks

Related questions

Q: Write equations for the preparation of n-pentane from a. n-pentyl bromļde b. sec-pentyl bromide…

A: We have to write for the preparation n-pentane from the following given compounds as follows in step…

Q: Write chemical equations expressing each of the following: (a) Preparation of o-nitrophenyl acetate…

A: “Since there are multiple questions and it is not mentioned that which one has to be solved so I am…

Q: Describe how the target molecule (butanone) can be synthesized in a high yield from butane.

A: The given final product is a ketone named butanone and the starting compound is an alkane. So when…

Q: Considering the products of your reaction between 4-aminophenol and acetic anhydride in aqueous…

A: We know that, when 4-aminophenol react with acetic anhydride then Acetylation take place on -NH2…

Q: In a paragraph form provide the experimental procedure of 3-benzoylpropionic acid reaction of…

A: The explanation is given below-

Q: What are the aldehydes that give the cannizzaro reaction? What are the reaction examples?

Q: give the results of the following compounds after reaction with Sodium Bicarbonate test a. propane…

Q: Outline methods for the preparation of acetophenone (phenyl methyl ketone) starting from the…

Q: Draw structural formulas for the a,ß-unsaturated aldehyde or ketone and the lithium diorganocuprate…

A: A question based on Gilmann reaction, which is to be accomplished.

Q: Starting with the following compounds, outline a practical synthesis of 1-butanol: 1. 2-chlorobutane…

A: Given, 1. 2-chlorobutane -----> 1-butanol 2. 1-butyne -------> 1-butanol

Q: Differentiate between the following statements: 1. Nucleophilic 1,2 and 1,4 addition to a,ß-…

A: 1,2 and 1,4 nucleophilic addition reaction gives simple addition product. Both reaction undergo…

Q: Write down the reaction of acetaldehyde with the following. |Tollens' reagent

A: Reaction of acetaldehyde with tollens reagent

Q: Beginning with the correct organic halide and benzophenone show how one would prepare…

Q: Draw structural formulas for an aldehyde or ketone and alkyl (or aryl) bromide that could be used in…

A: Alkyl magnesium bromide is known as a Grignard reagent. The Grignard reagent is a very useful…

Q: Show how the benzoic acid can be prepared from benzene:

A: Benzoic acid can be prepared from benzene by a 2 step process shown below:

Q: . The authenticity of ethyl alcohol is confirmed by the reactions: A) Dehydration in the presence of…

Q: Apply retrosynthetic analysis to guide the preparation of each of the following compounds from the…

A: While converting from 1 compound to another, organic reagents are used.

Q: Eugenol is the component responsible for the odor of cloves, which are dried flower buds of the…

Q: true or false. Considering the open-chain structures of carbohydrates, the carbon in the carbonyl…

Q: N,N- Dimethyl aniline reacts with Diazotized Sulfanilic acid to form Methyl Orange

Q: If NaOH were reacted with the given molecule, could it react with the epoxide to form a vicinal…

A: Epoxide reacts with sodium hydroxide to give vicinal diol and carbonyl groups (only aldehyde and…

Q: Draw structural formulas for the α,β-unsaturated aldehyde or ketone and the lithium diorganocuprate…

A: The reaction of a α, β-unsaturated aldehyde and Gilman reagent is a vital tool in organic synthesis.

Q: When separating the two products (benzoic acid and benzyl alcohol) in the Cannizzaro reaction, you…

A: Cannizaro reaction is a type of reaction in which aldehyde or ketone without alpha hydrogens react…

Q: Suggest the synthetic pathway to prepare the following compounds starting from 2- phenylethanol.…

A: Concept - In the above reaction- a) here we will use concentrated H2SO4, as it will convert alcohol…

Q: What would be the result of 2-carboxybenzaldehyde in the following (POSITIVE or NEGATIVE)…

A: 2-carboxybenzaldehyde (POSITIVE or NEGATIVE) Fehling's Test- Negative Baeyer's Test - positive…

Q: Write A if the test is specific for aldehydes, B if it is specific for ketones, C if both will react…

A: The test whether it is used for aldehyde or ketone or both is given below.

Q: Predict the product, if any, of reaction between propanoyl chloride and aniline.

A: In this question,we have to write the reaction between propanoyl chloride and aniline

Q: When alcohol A is heated with base as shown below, the expected epoxide does not form. Explain why…

Q: Explain why the acid-catalyzed dehydration of an alcohol is a reversible reaction, whereas the…

A: Generally, electrophile attack is the first step in the electrophilic addition of alcohol. The acid…

Q: Which alkyl bromide should be used in the synthesis of malonic ester with: a. Propanoic acid b.…

A: Solution- The alkyl bromides should be used in the malonic ester synthesis of given carboxylic acids…

Q: Show the chemical equation of N,N- Dimethyl aniline reacts with Diazotized Sulfanilic acid to form…

A: Reaction : When Diazotised sulphanilic acid react with N,N-dimethylaniline, it is first…

Q: Show how the m-chlorobenzenesulfonic acid can be synthesized from benzene:

A: The mechanism in which m-chlorobenzenesulfonic acid can be synthesized from benzene has to be…

Q: Draw a structural formula for the product of the aldol reaction of compound and for the…

A: The structural formula for the product of the aldol reaction of the compound and for the a…

Q: Write a single equilibrium reaction that is appropriate for both reactions and discuss the…

A: Esterification reaction: When an alcohol and carboxylic acid are heated in presence of a mineral…

Q: What functional group would be present in the product (the main organic product) of a reaction…

A: Given is reaction between ketone and grignard reagent.

Q: A Wittig reaction occurs when 4-methylbenzaldehyde and benzyltriphenylphosphonium chloride are…

A: wittig reaction used to preparation of alkene from a reaction between carbonyl (aldehyde or…

Q: 1. 2-chlorobutane 2. 1-butyne

A: 1. 2-chorobutane ----> 1-butanol 2. 1- butyne --------> 1- butanol

Q: Comment on the similarities or differences on the delocalization between oxazole and pyrazole

A: Similarities : a. In both cases five resonating structures can be drawn. b. In both cases one ring…

Q: Discuss comprehensively whether the circled functional group is an activator or deactivator during…

A: A question based on substitution aromatic electrophilic reaction, which is to be accomplished.

Q: By means of a series of equations outline a synthesis for each of the compounds from the indicated…

Q: What aldehyde or ketone is needed to prepare attached alcohol by metal hydride reduction?

A: Secondary alcohol can prepared by the reduction of ketone in the presence of metal hydride and…

Q: 1. Illustrate the Synthesis or Preparation of Benzoic Acid from the oxidation of Benzaldehyde with…

A: a) The reactant is Benzaldehyde. The structure of the reactant is,

Q: Draw a structural formula for the molecular (not ionic) compound that forms when 2-ethylbenzoic…

A: Answer A: In this reaction, the major product is A, which is non ionic.

Q: Which of the following sets of reagents would not be an acceptable method for the preparation of…

A: Please find your solution below : Ethyl acetate comes under the category of organic compounds called…

Q: Why are aldehydes more reactive with Schiff's Reagent and 2,4-dinitrophenylhydrazine than ketones?

A: In Schiff's reagent the sulfur in the bisulfite ion acts as a nucleophile and adds to the carbonyl…

Q: Identify the two compounds below that can be prepared from the reaction between a Grignard reagent…

Q: In a benzopinacolone synthesis, if the crude product obtained at the end of the reaction has a brown…

A: Interpretation - In a benzo pinacolone synthesis, if the crude product obtained at the end of the…

Concept explainers

NMR Spectroscopy

NMR stands for Nuclear Magnetic Resonance in which the study of different molecules is done based on the interaction of radiofrequency electromagnetic radiations with the nuclei of molecules placed in a strong magnetic field. A precise study of spectra of visible light and all bands of electromagnetic radiation is called spectroscopy.

Question

Draw structural formulas for the a,ß-unsaturated aldehyde or ketone and the lithium diorganocuprate (Gilman reagent) that could be
used in a synthesis of the compound shown below.

Expert Solution

Step 1

The product formed is given as,

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 5 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Draw structural formulas for the α,β-unsaturated aldehyde or ketone and the lithium diorganocuprate (Gilman reagent) that could be used in a synthesis of the compound shown below.
Draw structural formulas for the a,ß-unsaturated aldehyde or ketone and the lithium diorganocuprate (Gilman reagent) that could be used in a synthesis of the compound shown below. You do not have to consider stereochemistry. • In cases where there is more than one answer, just give one. • If a structure has a copper-lithium bond, draw the lithium ion in a separate sketcher. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple reactants using the + sign from the drop-down menu. . 89 4 Sa F
Draw a structural formula for the product of the reaction shown.
Draw structural formulas for the a,ß-unsaturated aldehyde or ketone and the lithium diorganocuprate (Gilman reagent) that could be used in a synthesis of the compound shown below. • • • • You do not have to consider stereochemistry. In cases where there is more than one answer, just give one. If a structure has a copper-lithium bond, draw the lithium ion in a separate sketcher. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple reactants using the + sign from the drop-down menu. -CH2 ? √n [ ChemDoodle ChemDoodle + n [
Using chemical structures draw the complete chemical reaction of Acetone with benzaldehyde under basic conditions, provide both the major and minor products.
The reaction that occurs when the benzaldehyde you have is reacted in a basic environment is called the Cannizzaro reaction, and when it is reacted with cyanide, it is called benzoin. It Explain the reason by writing the reaction mechanisms of the reactions.
a) Write out the first 3 steps only(to the tetrahedral intermediate shown) in the 6-step arrow pushing mechanism showing how ethyl propanoate is hydrolyzed in acid to form propanoic acidand ethanol. b) NaOH/H2O also serveto hydrolyze an ester; briefly explain why NaOH/H2Ois generally preferable.
Write the product formed as a result of the reaction given below.
In paragraph/essay form:Provide an explanation (in detail) on how base catalysts speed up nucleophilic reactions of carbonyl compounds.
Draw the molecular structure of p-nitrophenol in an acidic solution and in an alkaline solution.
Depict a synthesis for the following product starting from benzene and any other organic of inorganic material.
Explain the experimental procedure of the laboratory preparation of the synthesis of benzyl chloride from phenol (paragraph form) Explain the chemistry behind the synthesis of benzyl chloride from phenol (paragraph form)