Answered: Draw the mechanism for the following…

Draw the mechanism for the following reaction and account for the relative stereochemistry. MeO₂C MeO₂C CO₂Me Pd2(dba)3.CHCI 3 Ph3P, ACOH MeO₂C

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions

Section30.7: Sigmatropic Rearrangements

Problem 7P

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Question

Draw the mechanism for the following reaction and account for the relative stereochemistry.
MeO₂C
MeO₂C CO₂Me
Pd2(dba)3.CHCI 3
Ph3P, ACOH
MeO₂C

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