Draw the structure(s) of the major organic product(s) of the following reaction after aqueous workup. H₂N Benzocaine topical anesthetic • You do not have to consider stereochemistry. • Include counter-ions, e.g., Na+, I, in your submission, but draw them in their own separate sketcher. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu. .
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- Draw the structure(s) of the major organic product(s) of the following reaction. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If the reaction produces a racemic mixture, draw both stereoisomers. • Include counter-ions, e.g., Na+, I, in your submission, but draw them in their own separate sketcher. • Omit products derived from the acidic or basic reagent itself, e.g. HN(i-Pr)2 derived from N(i-Pr)₂¯. • If substantial starting material is present at the end of the reaction, include it in the products. If no reaction occurs, draw the organic starting material. + ▼ Dilute aqueous NaOH ChemDoodle Sn [FComplete the generic mechanism for an electrophilic aromatic substitution (EAS) reaction using E as the electrophile, and show how the sigma complex is resonance stabilized. Use curved arrows to show the mechanism and the conversion between resonance structures. Make sure to add any missing charges. Note the use of a generic base (B) in the last step. Then, label the reaction coordinate diagram for a typical EAS reaction by correctly placing the structures on the diagram. Step 1: add a curved arrow. Select / |||||| Draw CH Rings Groups More Erase slow WEDraw the structure(s) of the major organic product(s) of the following reaction. Br 1. acetonitrile / reflux 2. aqueous HCI . You do not have to consider stereochemistry. . You do not have to explicitly draw H atoms. . Do not include lone pairs in your answer. They will not be considered in the grading. . Do not include the amine from which the enamine was derived. If no reaction occurs, draw the organic starting material. ⚫ Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu. ? ChemDoodle
- Draw the structure(s) of the major organic product(s) obtained after workup of the following reaction. + H₂N Basic workup . You do not have to consider stereochemistry. • If no reaction occurs, draw the organic starting material. • Draw structure(s) of product(s) after workup to neutralize acid. . . Include counter-ions, e.g., Na+, I, in your submission, but draw them in their own separate sketcher. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. + n ?Draw the structure(s) of the major organic product(s), including counterions, of the following reaction. HBr H₂O You do not have to consider stereochemistry. • Include counter-ions, e.g., Na*, I, in your submission, but draw them in their own separate sketcher. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. ⚫ Separate multiple products using the + sign from the drop-down menu. n [F FDraw the structure(s) of the major organic product(s) of the following reaction after aqueous workup. CH3 CH3 • You do not have to consider stereochemistry. • Include counter-ions, e.g., Na", I, in your submission, but draw them in their own separate sketcher. • If no reaction occurs, draw the organic starting material. Draw one structure per sketcher. Add additional sketchers using the drop- down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu.
- Draw the structure(s) of the major organic product(s) obtained after workup of the following reaction. HNON-E-CHS 1 eq. HCI • You do not have to consider stereochemistry. If no reaction occurs, draw the organic starting material. Include counter-ions, e.g., Na+, I, in your submission, but draw them in their own separate sketcher. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.Draw a structure for the organic produet(s) of the following reaction. SCH3 H,O2, "OH • You do not have to consider stereochemistry. • Include counter-ions, e.g., Na", I, in your submission, but draw them in their own separate sketcher. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu. P.Draw the structure(s) of the major organic product(s) of the following reaction after aqueous workup. NH2 + CH3 CH3 • You do not have to consider stereochemistry. • • If no reaction occurs, draw the organic starting material. ⚫ Include counter-ions, e.g., Na+, I", in your submission, but draw them in their own separate sketcher. • • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the + sign from the drop-down menu. On √n [ ? Ⓡ ChemDoodleⓇ
- Draw the structure(s) of the major organic product(s) of the following reaction after aqueous workup. O + + II... • You do not have to consider stereochemistry. • Include counter-ions, e.g., Na+, I, in your submission, but draw them in their own separate sketcher. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. H₂N Benzocaine topical anesthetic ? YDraw structures for the carbonyl electrophile and enolate nucleophile that react to give the enone below. CE O • You do not have to consider stereochemistry. • Draw the enolate ion in its carbanion form. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple reactants using the + sign from the drop-down menu. ● [... ?2. Check the reaction given below. Benzoic acid is synthesized from benzene. Suggest a synthetic route from benzene to benzoic acid with the reactions you learn in electrophillic aromatc substitution reactions. PS: This is not a one step reaction !!! .COOH 3. You all know the carbonyl structure. It is carbon atom double bonded to the oxygen atom. a. Draw the dipol moment of the carbonyl structure. b. Here are two different carbonyl bearing molecules. With the knowledge you learned so far explain which one is more stable and why? CH3 H3C H3C b. а. 4. Is it possible to achieve this reaction directly? Explain your reasons. *CH3