Ethanol + hydrochloric acid sodium hydroxide + acetic acid sodium hydroxide + ethyne ammonia + acetic acid protonated ethanol + chloride water and sodium acetate water and sodium ethynide ammonium acetate

Chemistry: An Atoms First Approach
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Author:Steven S. Zumdahl, Susan A. Zumdahl
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Chapter13: Acids And Bases
Section: Chapter Questions
Problem 2ALQ: Differentiate between the terms strength and concentration as they apply to acids and bases. When is...
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Use table 3.1 of acidity to determine the position of equilibrium in each acid-base reaction either to be shifted to the right or to be shifted to the left. If you do not know names google them, draw them, remember them.

Ethanol hydrochloric acid
sodium hydroxide + acetic acid
sodium hydroxide + ethyne
ammonia + acetic acid
protonated ethanol + chloride
water and sodium acetate
water and sodium ethynide
ammonium acetate
Transcribed Image Text:Ethanol hydrochloric acid sodium hydroxide + acetic acid sodium hydroxide + ethyne ammonia + acetic acid protonated ethanol + chloride water and sodium acetate water and sodium ethynide ammonium acetate
TABLE 3.1 RELATIVE STRENGTH OF SELECTED ACIDS AND THEIR CONJUGATE BASES
Strongest acid
Increasing acid strength
Weakest acid
Acid
HSbF6
HI
H₂SO4
HBr
HCI
C6H5SO₂H
(CH3)₂OH
(CH3)₂C=OH
(CH3)OH2
H3O+
HNO3
CF3CO₂H
HF
C6H5CO₂H
CH5NH3
CH3CO₂H
H₂CO3
CH3COCH₂COCH 3
NH
CH5OH
HCO3
CH3NH3
H₂O
CH3CH₂OH
(CH3)3COH
CH3COCH 3
HC=CH
CsH5NH2
H₂
(i-Pr)₂NH
NH3
CH₂=CH₂
CH3CH3
Approximate pKa
<-12
-10
-9
-9
-7
-6.5
-3.8
-2.9
-2.5
-1.74
-1.4
0.18
3.2
4.21
4.63
4.75
6.35
9.0
9.2
9.9
10.2
10.6
15.7
16
18
19.2
25
31
35
36
38
44
50
Conjugate
Base
SbF
r
HSO4
Br
CI
CH5SO3
(CH3)20
(CH3)2C=O
CH3OH
H₂O
NO3
CF3CO₂
F
CH5CO₂
CsH5NH2
CH3CO₂
HCO3
CH3COCHCOCH 3
NH3
CH5O
CO²-
CH3NH2
HO™
CH3CH₂O
(CH3)3CO
CH₂COCH 3
HC=C
CoH5NH
H™
(i-Pr)₂N
™NH₂
CH₂=CH
CH₂CH₂
Weakest base
Increasing base strength
Strongest base
Transcribed Image Text:TABLE 3.1 RELATIVE STRENGTH OF SELECTED ACIDS AND THEIR CONJUGATE BASES Strongest acid Increasing acid strength Weakest acid Acid HSbF6 HI H₂SO4 HBr HCI C6H5SO₂H (CH3)₂OH (CH3)₂C=OH (CH3)OH2 H3O+ HNO3 CF3CO₂H HF C6H5CO₂H CH5NH3 CH3CO₂H H₂CO3 CH3COCH₂COCH 3 NH CH5OH HCO3 CH3NH3 H₂O CH3CH₂OH (CH3)3COH CH3COCH 3 HC=CH CsH5NH2 H₂ (i-Pr)₂NH NH3 CH₂=CH₂ CH3CH3 Approximate pKa <-12 -10 -9 -9 -7 -6.5 -3.8 -2.9 -2.5 -1.74 -1.4 0.18 3.2 4.21 4.63 4.75 6.35 9.0 9.2 9.9 10.2 10.6 15.7 16 18 19.2 25 31 35 36 38 44 50 Conjugate Base SbF r HSO4 Br CI CH5SO3 (CH3)20 (CH3)2C=O CH3OH H₂O NO3 CF3CO₂ F CH5CO₂ CsH5NH2 CH3CO₂ HCO3 CH3COCHCOCH 3 NH3 CH5O CO²- CH3NH2 HO™ CH3CH₂O (CH3)3CO CH₂COCH 3 HC=C CoH5NH H™ (i-Pr)₂N ™NH₂ CH₂=CH CH₂CH₂ Weakest base Increasing base strength Strongest base
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