Examining the crystal structure of CsCl (Caesium Chloride), the Cs+ions form the 8 corners of a cube and the Cl−ion is a the center of the cube. From first-principles calculation, it was determined that the lattice constant of CsCl is 4.209 ̊A. (a) Calculate in detail the electrostatic force exerted by all the Cs+ atoms to the Cl−atom; (b) Assuming that 1 Cs+atom is missing in crystal structure (crystal is said to have a defect), calculate in detail what will be the net electrostatic force on the Cl−ion due to the remaining Cs+ions.
Examining the crystal structure of CsCl (Caesium Chloride), the Cs+ions form the 8 corners of a cube and the Cl−ion is a the center of the cube. From first-principles calculation, it was determined that the lattice constant of CsCl is 4.209 ̊A. (a) Calculate in detail the electrostatic force exerted by all the Cs+ atoms to the Cl−atom; (b) Assuming that 1 Cs+atom is missing in crystal structure (crystal is said to have a defect), calculate in detail what will be the net electrostatic force on the Cl−ion due to the remaining Cs+ions.
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter4: Energy And Chemical Reactions
Section: Chapter Questions
Problem 122QRT
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Examining the crystal structure of CsCl (Caesium Chloride), the Cs+ions form the 8 corners of a cube
and the Cl−ion is a the center of the cube. From first-principles calculation, it was determined that the
lattice constant of CsCl is 4.209 ̊A. (a) Calculate in detail the electrostatic force exerted by all the Cs+
atoms to the Cl−atom; (b) Assuming that 1 Cs+atom is missing in crystal structure (crystal is said
to have a defect), calculate in detail what will be the net electrostatic force on the Cl−ion due to the
remaining Cs+ions.
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