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Chemistry: An Atoms First Approach

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter4: Molecular Structure And Orbitals

Section: Chapter Questions

Problem 13Q

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Fill in the table for the following compounds.
hybridization
electronic geometry
molecular geometry
:0-c=0:
ideal bond angles
polar or nonpolar
Give correct detailed
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Methionine, CH3SCH2CH2CH(NH2)CO2H, is an amino acid found in proteins. The Lewis structure of this compound is shown below. What is the hybridization type of each carbon, oxygen, the nitrogen, and the sulfur?
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Strike-anywhere matches contain a layer of KClO3 and a layer of P4S3. The heat produced by the friction of striking the match causes these two compounds to react vigorously, which sets fire to the wooden stem of the match. KCIO3 contains the ClO3 ion. P4S3 is an unusual molecule with the skeletal structure. (a) Write Lewis structures for P4S3 and the ClO3 ion. (b) Describe the geometry about the P atoms, the S atom, and the Cl atom in these species. (c) Assign a hybridization to the P atoms, the S atom, and the Cl atom in these species. (d) Determine the oxidation states and formal charge of the atoms in P4S3 and the ClO3 ion.
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What would you expect to be the electron-group arrangement around atom A in the following case? Give the ideal bond angle and the direction of any expected deviation.h5sil102302Electron-group arrangement:linearbent (V-shaped)trigonal bipyramidal Ideal bond angle:°Expected angle deviation:smallerlargernone
Determine the hybridization of all atoms on the following structure by pointing to За each atom with a small arrow labeling the hybridization 3b) lone pairs Draw the Lewis structure corresponding to the structure above showing all atoms and 3c) Consider the same structure with each atom labeled below: e Determine the angles of the following bonds on the structure Оa-Cb-Сс: Сс-Cd-Ce: Ce-Cf-Cg: 3d) (potnts) Rank the following selected bonds on the structure above in order of increasing bond length. Specify which one is the shortest and which one is the longest Oa-Cb; Cc-Cd; Cd-Ce; Cf-Cg
What would you expect to be the electron-group arrangement around atom A in the following case? Give the ideal bond angle and the direction of any expected deviation. X=AX Electron-group arrangement: trigonal bipyramidal bent (V-shaped) linear Ideal bond angle: O Expected angle deviation: none smaller larger
For each of the following molecules, draw the Lewis structure, predict the molecular shape using VSEPR method, and propose the orbital hybridization on the central atom of each molecule. (a) BeF2 (b) GeF2 (c) AsCl3 (d) BrCl3 (e) GeCl4 (f) SeCl4 (g) AsCls (h) BrF5 (i) SF, (j) XeF4
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