Hydrogen sulfide (H2SH2S) is a common and troublesome pollutant in industrial wastewaters. One way to remove H2SH2S is to treat the water with chlorine, in which case the following reaction occurs: H2S(aq)+Cl2(aq)→S(s)+2H+(aq)+2Cl−(aq)H2S(aq)+Cl2(aq)→S(s)+2H+(aq)+2Cl−(aq) The rate of this reaction is first order in each reactant. The rate constant for the disappearance of H2SH2S at 28 ∘C∘C is 3.5×10−2 M−1s−1 If at a given time the concentration of H2SH2S is 2.2×10−4 M and that of Cl2Cl2 is 0.029 M , what is the rate of formation of Cl−Cl−?
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
Hydrogen sulfide (H2SH2S) is a common and troublesome pollutant in industrial wastewaters. One way to remove H2SH2S is to treat the water with chlorine, in which case the following reaction occurs:
H2S(aq)+Cl2(aq)→S(s)+2H+(aq)+2Cl−(aq)H2S(aq)+Cl2(aq)→S(s)+2H+(aq)+2Cl−(aq)
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