Iron (III) can be separated from other metals, such as chromium, by extraction into ether from a strong aqueous HCl solution. If 50 mL of aqueous HCl containing 0.25 g of iron(III) is treated with 150 mL of ether in a one-shot process, how many milligrams of iron is left in the aqueous phase? Use a value of 50 for the distribution ratio.
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Iron (III) can be separated from other metals, such as chromium, by extraction into ether from
a strong aqueous HCl solution. If 50 mL of aqueous HCl containing 0.25 g of iron(III) is treated
with 150 mL of ether in a one-shot process, how many milligrams of iron is left in the aqueous
phase? Use a value of 50 for the distribution ratio.
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- 1. A 0.9882 gram sample of iron ore is dissolved, the iron reduced to Fe2+, and the solution was titrated with 36.40 mL of 0.02065 M KMnO4 in acid solution. (a) Write the titration reaction. (b) Calculate the %FeO (M.M. = 71.85) in the sample. 2. A sample of primary standard grade K2Cr2O7 (MM = 294.20) weighing 0.2153 g is dissolved, the solution acidified and excess KI added. The liberated I2 requires 44.86 mL of the Na2S2O3 for titration. (a) Write the titration reaction. (b) Calculate the molarity of the titrant solution. Box the final answer.1. A 0.9882 gram sample of iron ore is dissolved, the iron reduced to Fe2+, and the solution was titrated with 36.40 mL of 0.02065 M KMnO4 in acid solution. (a) Write the titration reaction. (b) Calculate the %FeO (M.M. = 71.85) in the sample. 2. A sample of primary standard grade K2Cr2O7 (MM = 294.20) weighing 0.2153 g is dissolved, the solution acidified and excess KI added. The liberated I2 requires 44.86 mL of the Na2S2O3 for titration. (a) Write the titration reaction. (b) Calculate the molarity of the titrant solution.A Chemist collected a 0.4891-g sample of an ore for Fe determination by a redox titration with K2Cr2O7.The ore was carefully crushed prior to weighing and dissolved in HCl and using a Jones reductor the ironin the sample was brought into the +2 oxidation state. After titration with diphenylamine sulfonic acid,itrequired 36.92 mL of 0.02153 M K2Cr2O7 to reach the end point. Show your solution why 77.86% is the iron content of the ore as %w/w Fe2O3.
- A Chemist collected a 0.4891-g sample of an ore for Fe determination by a redox titration with K2Cr2O7.The ore was carefully crushed prior to weighing and dissolved in HCl and using a Jones reductor the ironin the sample was brought into the +2 oxidation state. After titration with diphenylamine sulfonic acid,itrequired 36.92 mL of 0.02153 M K2Cr2O7 to reach the end point. Calculate the iron content of the ore as%w/w Fe2O3Chromel is an alloy composed of nickel, iron, and chromium. A 0.6392-g sample was dissolved and diluted to 250.0 mL. When a 50.00-mL aliquot of 0.05173 M EDTA was mixed with an equal volume of the diluted sample, all three ions were chelated, and a 5.15-mL back-titration with 0.06139 M copper(II) was required. The chromium in a second 50.0-mL aliquot was masked through the addition of hexamethylenetetramine; titration of the Fe and Ni required 34.27 mL of 0.05173 M EDTA. Iron and chromium were masked with pyrophosphate in a third 50.0-mL aliquot, and the nickel was titrated with 24.31 mL of the EDTA solution. Calculate the percentages of nickel, chromium, and iron in the alloy. Percentage of nickel = % Percentage of iron = Percentage of chromium = % 10A pure oxide of iron weighing 1.000 g is fused with K2S2O7 and the fused material dissolved in acid. The Fe3+ is reduced with SnCl2, HgCl2 is added, and the Fe2+ titrated with 0.1667 M K2Cr2O7 solution, requiring 12.96 mL. What was the formula of the original oxide?
- (i) Write the composition of bleaching powder.(ii) What happens when NaCl is heated with conc. H2SO4 in the presenceof MnO2. Write the chemical equation.What mass of solid Lanthanum (III) oxalate nonahydrate { La2 ( C2O4 )3 ∙ 9 H2O } can be obtained from 650 mL of 0.0170 M aqueous solution of LaCl3 by adding a stoichiometric amount of sodium oxalate ? with solution/explanationA mined alloy sample weighing 2.0840 g is dissolved in minimal amounts of concentrated HNO3 before diluted to 50 mL. Ten mL of this diluted sample was titrated using 0.091 M KSCN and required 14.20 mL to reach the endpoint. Calculate the concentration of silver (%w/w) in the mined alloy. (Hint: A dilution factor (DF) is needed in the formula.) Titration reaction: Agt + SCN- → A9SC'N(s) FW: Ag = 107.87 %3D
- The amount of Fe in a 0.4891-g sample of an ore is determined by titrating with K2Cr207. After dissolving the sample in HCI, the iron is brought into a +2 oxidation state using a Jones reductor. Titration to the diphenylamine sulfonic acid end point requires 36.92 mL of 0.02153 M K2Cr207. Report the ore's iron content as %w/w Fe203. In this problem, which is the titrant? K2Cr207 diphenylamine sulfonic acid Fe203 HCI Fe2+The amount of Fe in a 0.4891-g sample of an ore is determined by titrating with K2Cr207. After dissolving the sample in HCI, the iron is brought into a +2 oxidation state using a Jones reductor. Titration to the diphenylamine sulfonic acid end point requires 36.92 mL of 0.02153 M K2Cr207. Report the ore's iron content as %w/w Fe203. In this problem, which is the indicator ? Fe2+ Fe203 HCI K2Cr207 diphenylamine sulfonic acidA 2.559 g sample containing both Fe and V was dissolved under conditions that converted the elements to Fe(III) and V(V). The solution was diluted to 500.0 mL and a 50.0 mL aliquot was passed through a Walden 4+ reductor and titrated with 17.74 mL of 0.100 M Ce . A second 50.0 mL aliquot was passed through a Jones reductor and required 44.67 mL of the same Ce4+ solution to reach an endpoint. Calculate the percentage of Fe2O3 and V2O5 in the sample.