Lead (II) sulfide (PbS, an insoluble salt, Ksp = 3.4 x 10-28) was used as a black pigment by the artist Leonardo. a) Lead ions will form the following complex ion, [Pb(Cl)4] 2- ,Kf= 2.5 x 1015with the addition of NaCl) causing the lead sulfide to dissolve. What is the molar solubility of lead sulfide if you already have the precipitate when a 1.2 M solution of NaCl is added to the precipitate (eliminate spectator ions)? If a beaker contains 0.1 M lead ions and sulfide ions and 1.4 M chloride ions. Write the 2 reactions that occur with the lead ions. Which reaction takes precedence?

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Chapter17: Solubility And Complex-ion Equilibria
Section: Chapter Questions
Problem 17.7QP
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1. Lead (II) sulfide (PbS, an insoluble salt, Ksp = 3.4 x 10-28) was used as a black
pigment by the artist Leonardo.
a) Lead ions will form the following complex ion, [Pb(Cl)4] ²- ,Kf = 2.5 x 1015with
the addition of NaCl) causing the lead sulfide to dissolve. What is the molar
solubility of lead sulfide if you already have the precipitate when a 1.2 M solution of
NaCl is added to the precipitate (eliminate spectator ions)? If a beaker contains 0.1 M
lead ions and sulfide ions and 1.4 M chloride ions. Write the 2 reactions that occur
with the lead ions. Which reaction takes precedence?
Transcribed Image Text:1. Lead (II) sulfide (PbS, an insoluble salt, Ksp = 3.4 x 10-28) was used as a black pigment by the artist Leonardo. a) Lead ions will form the following complex ion, [Pb(Cl)4] ²- ,Kf = 2.5 x 1015with the addition of NaCl) causing the lead sulfide to dissolve. What is the molar solubility of lead sulfide if you already have the precipitate when a 1.2 M solution of NaCl is added to the precipitate (eliminate spectator ions)? If a beaker contains 0.1 M lead ions and sulfide ions and 1.4 M chloride ions. Write the 2 reactions that occur with the lead ions. Which reaction takes precedence?
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