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Measuring total pressure is a convenient way to monitor gas reaction: 2NOCl(g) → 2NO(g) + Cl2(g). The rate of the reaction depends on the concentration of the reactant, which is proportional to the partial pressure of the reactant. Derive a relation connecting its velocity above reaction with initial pressure, P0, and total pressure, Pt, at time t.(Hint: Assume the reaction is 2nd order. Make a table with initial (t0) and final values ​​(t) of the moles of NOCl, NO, and Cl2, and construct the ideal gas equations for both cases. Use the ideal gas equation for t0 so that calculate the initial concentration of NOCl and substitute this value into the equation of ideal gases for t

Measuring total pressure is a convenient way to monitor gas reaction: 2NOCl(g) → 2NO(g) + Cl2(g). The rate of the reaction depends on the concentration of the reactant, which is proportional to the partial pressure of the reactant. Derive a relation connecting its velocity above reaction with initial pressure, P0, and total pressure, Pt, at time t.(Hint: Assume the reaction is 2nd order. Make a table with initial (t0) and final values ​​(t) of the moles of NOCl, NO, and Cl2, and construct the ideal gas equations for both cases. Use the ideal gas equation for t0 so that calculate the initial concentration of NOCl and substitute this value into the equation of ideal gases for t

Chemistry
Chemistry
9th Edition
ISBN:9781133611097
Author:Steven S. Zumdahl
Publisher:Steven S. Zumdahl
Chapter12: Chemical Kinetics
Section: Chapter Questions
Problem 5ALQ: Consider the following statements: In general, the rate of a chemical reaction increases a bit at...
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Measuring total pressure is a convenient way to monitor gas reaction: 2NOCl(g) → 2NO(g) + Cl2(g). The rate of the reaction depends on the concentration of the reactant, which is proportional to the partial pressure of the reactant. Derive a relation connecting its velocity above reaction with initial pressure, P0, and total pressure, Pt, at time t.(Hint: Assume the reaction is 2nd order. Make a table with initial (t0) and final values ​​(t) of the moles of NOCl, NO, and Cl2, and construct the ideal gas equations for both cases. Use the ideal gas equation for t0 so that calculate the initial concentration of NOCl and substitute this value into the equation of ideal gases for t)

 

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