Organic Chemistry 9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: John E. McMurry
1 Structure And Bonding 2 Polar Covalent Bonds; Acids And Bases 3 Organic Compounds: Alkanes And Their Stereochemistry 4 Organic Compounds: Cycloalkanes And Their Stereochemistry 5 Stereochemistry At Tetrahedral Centers 6 An Overview Of Organic Reactions 7 Alkenes: Structure And Reactivity 8 Alkenes: Reactions And Synthesis 9 Alkynes: An Introduction To Organic Synthesis 10 Organohalides 11 Reactions Of Alkyl Halides: Nucleophilic Substitutions And Eliminations 12 Structure Determination: Mass Spectrometry And Infrared Spectroscopy 13 Structure Determination: Nuclear Magnetic Resonance Spectroscopy 14 Conjugated Compounds And Ultraviolet Spectroscopy 15 Benzene And Aromaticity 16 Chemistry Of Benzene: Electrophilic Aromatic Substitution 17 Alcohols And Phenols 18 Ethers And Epoxides; Thiols And Sulfides 19 Aldehydes And Ketones: Nucleophilic Addition Reactions 20 Carboxylic Acids And Nitriles 21 Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions 22 Carbonyl Alpha-substitution Reactions 23 Carbonyl Condensation Reactions 24 Amines And Heterocycles 25 Biomolecules: Carbohydrates 26 Biomolecules: Amino Acids, Peptides, And Proteins 27 Biomolecules: Lipids 28 Biomolecules: Nucleic Acids 29 The Organic Chemistry Of Metabolic Pathways 30 Orbitals And Organic Chemistry: Pericyclic Reactions 31 Synthetic Polymers Chapter26: Biomolecules: Amino Acids, Peptides, And Proteins
26.1 Structures Of Amino Acids 26.2 Amino Acids And The Henderson–hasselbalch Equation: Isoelectric Points 26.3 Synthesis Of Amino Acids 26.4 Peptides And Proteins 26.5 Amino Acid Analysis Of Peptides 26.6 Peptide Sequencing: The Edman Degradation 26.7 Peptide Synthesis 26.8 Automated Peptide Synthesis: The Merrifield Solid-phase Method 26.9 Protein Structure 26.10 Enzymes And Coenzymes 26.11 How Do Enzymes Work? Citrate Synthase 26.SE Something Extra Section26.SE: Something Extra
Problem 19VC: Identify the following amino acids: Problem 20VC Problem 21VC: Isoleucine and threonine are the only two amino acids with two chirality centers. Assign R or S... Problem 22VC Problem 23VC: Give the sequence of the following tetrapeptide: Problem 24MP Problem 25MP: The chloromethylated polystyrene resin used for Merrifield solidphase peptide synthesis is prepared... Problem 26MP Problem 27MP Problem 28MP Problem 29AP: Except for cysteine, only S amino acids occur in proteins. Several R amino acids are also found in... Problem 30AP Problem 31AP Problem 32AP: Show the structures of the following amino acids in their zwitterionic forms: (a) Trp (b) Ile (c)... Problem 33AP Problem 34AP: Using both three- and one-letter codes for amino acids, write the structures of all possible... Problem 35AP Problem 36AP: Show how you could use the acetamidomalonate method to prepare the following amino acids: (a)... Problem 37AP Problem 38AP: Show how you could prepare the following amino acids enantioselectively: (a) Pro (b) Val Problem 39AP Problem 40AP: Predict the product of the reaction of valine with the following reagents: (a) CH3CH2OH, acid (b)... Problem 41AP Problem 42AP Problem 43AP: Propose two structures for a tripeptide that gives Leu, Ala, and Phe on hydrolysis but does not... Problem 44AP: Show the steps involved in a synthesis of Phe-Ala-Val using the Merrifield procedure. Problem 45AP Problem 46AP Problem 47AP Problem 48AP: Which of the following amino acids are more likely to be found on the exterior of a globular... Problem 49AP: Leuprolide is a synthetic nonapeptide used to treat both endometriosis in women and prostate cancer... Problem 50AP: The -helical parts of myoglobin and other proteins stop whenever a proline residue is encountered in... Problem 51AP Problem 52AP: Cytochrome c is an enzyme found in the cells of all aerobic organisms. Elemental analysis of... Problem 53AP Problem 54AP Problem 55AP Problem 56AP: What is the structure of a nonapeptide that gives the following fragments when cleaved? Trypsin... Problem 57AP: Oxytocin, a nonapeptide hormone secreted by the pituitary gland, functions by stimulating uterine... Problem 58AP: Aspartame, a nonnutritive sweetener marketed under such trade names as Equal, NutraSweet, and... Problem 59AP Problem 60AP Problem 61AP Problem 62AP Problem 59AP
Indicate the mechanism of Hofmann degradation of the compound N-(2-phenylethyl)butan-1-amine . Indicate the majority product.
Definition Definition Organic compounds with a nitrogen atom having a lone pair of electrons on it. Amines are derived from ammonia (NH 3 ), wherein hydrogen atoms are substituted by an aryl or alkyl group.
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