One can calculate the molar solubility of a conic marble sample, predominantly made of CaCO3, when exposed to acid rain with a pH of 4.34 using the following information: CaCO3) + H2O) + CO2la0) = Ca2*aq) + 2 HCO, (aq) K = ? CaCO36) = Ca2"nq) + CO,2"(a) Kp = 2.8 x 10 CO2laq) + 2 H2O) = H3O°uq) + HCO3'cam) K1 - 4,4 x 107 HCO3 (an) + H2O) =H3O*taq) + CO,²'wa) K2 = 4.7 x 1011 2 H2Ou= H3Oʻsao) + OH'aol Kw- 1.0 x 1014 A water sample from around the marble is collected into a conical container. Assuming that the calcium is purely from the marble sample, and basing your calculations off of the molar solubility, calculate how many grams of calcium are present in this water sample. Note that the cone has a base radius of 10.00mm and a height of 480.8mm. molar solubility of CaCO3 = M amount of calcium= --× 103 g

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter15: Complex Ion And Precipitation Equilibria
Section: Chapter Questions
Problem 63QAP: Marble is almost pure CaCO3. Acid rain has a devastating effect on marble statuary left outdoors....
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One can calculate the molar solubility of a conic marble sample, predominantly made of CACO3, when exposed to acid rain with a pH of 4.34 using the following information:
CaCO3(6) + H2O1) + CO2(aq)
Ca2+,
(aq)
+ 2 НСОЗ (аq)
K = ?
CaCO3(6) = Ca"(aq) + CO3“ (aq)
Ksp
= 2.8 x 109
CO2{aq) + 2 H2O) = H3O*(aq) + HCO3 (aq)
K1 = 4.4 x 10-7
HCO3 (aq) + H2O) = H30*(aq) + CO3 (aq)
K2 = 4.7 x 1011
2 H2O1) = H30* (aq) + OH (aq)
Kw
= 1.0 x 10-14
A water sample from around the marble is collected into a conical container. Assuming that the calcium is purely from the marble sample, and basing your calculations off of the molar solubility, calculate how many grams of calcium are
present in this water sample. Note that the cone has a base radius of 10.00mm and a height of 480.8mm.
molar solubility of CaCO3 =
M
amount of calcium
x 10-3 g
%3D
Transcribed Image Text:One can calculate the molar solubility of a conic marble sample, predominantly made of CACO3, when exposed to acid rain with a pH of 4.34 using the following information: CaCO3(6) + H2O1) + CO2(aq) Ca2+, (aq) + 2 НСОЗ (аq) K = ? CaCO3(6) = Ca"(aq) + CO3“ (aq) Ksp = 2.8 x 109 CO2{aq) + 2 H2O) = H3O*(aq) + HCO3 (aq) K1 = 4.4 x 10-7 HCO3 (aq) + H2O) = H30*(aq) + CO3 (aq) K2 = 4.7 x 1011 2 H2O1) = H30* (aq) + OH (aq) Kw = 1.0 x 10-14 A water sample from around the marble is collected into a conical container. Assuming that the calcium is purely from the marble sample, and basing your calculations off of the molar solubility, calculate how many grams of calcium are present in this water sample. Note that the cone has a base radius of 10.00mm and a height of 480.8mm. molar solubility of CaCO3 = M amount of calcium x 10-3 g %3D
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