Polyurethanes can be made by the step growth polymerization based on the reaction between isocyanates (R-N=C=O) and alcohols. Predict the repeat unit and draw the reaction mechanism for the polymerization of 4,4'-methylenebis(phenylisocyanate) and ethylene glycol. O=C=N- H -N=C=O 4,4'-methylenebis(phenylisocyanate) HO. OH ethylene glycol

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter31: Synthetic Polymers
Section31.SE: Something Extra
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Polyurethanes can be made by the step growth polymerization based on the reaction
between isocyanates (R-N=C=O) and alcohols. Predict the repeat unit and draw the reaction
mechanism for the polymerization of 4,4'-methylenebis (phenylisocyanate) and ethylene
glycol.
O=C=N-
-N=C=O
4,4'-methylenebis(phenylisocyanate)
HO
OH
ethylene glycol
Transcribed Image Text:Polyurethanes can be made by the step growth polymerization based on the reaction between isocyanates (R-N=C=O) and alcohols. Predict the repeat unit and draw the reaction mechanism for the polymerization of 4,4'-methylenebis (phenylisocyanate) and ethylene glycol. O=C=N- -N=C=O 4,4'-methylenebis(phenylisocyanate) HO OH ethylene glycol
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