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- Provide the mechanism for the following reaction (1) PhMgBr (2 equiv) (2) H3O+ workup OHDescribe the mechanism of the following reaction. 1) H2N NH2 (excess) SH SH `CO2H AcO 2) КОН 3) H +31. Which mechanism is correct for the following intramolecular substitution reaction? (a) (b) (c) 4- H-N H H N: H H₂N N: он --مرح CI CI CI H H CI N: NaOH N: CI *H :OH -- NH NH CNH на он NH NH
- Q5 (a) Justify the rate of reactions considering F as a Nu Alkyle halide Relative Rate Camments 200 0.02 79 200 920 100000OMe O OMe mechanism requires PdCl₂ (cat) A CUCI, O₂ H₂OOH - NH, Br2/KOH →product; 1. (a-hydroxy amide) Product of this Hoffmann bromamide reaction is : OH (a) Ph – Ĉ-CH3 (Ъ) Ph — CHO (c) Ph- CH3 (d) Ph – CH2 -NH2 NO2
- Propose a plausible mechanism for the followng reaction INa, NH3 (liq) 2 NH CI6. Complete reaction scheme below indicating reagents, catalysts and conditions, and side product trigil bezinslog si6101fon 290b 1l (b Senines levirba 6 gaubong nasamots gniwollot ads to doinW 01 sniowl (6 CH3 40 CH3 Scansgowi (d Ege nodie) ( nsgyxo (b NO₂ 19m02 2i gniwollet sits to mainW II HO10. practice q 10 Compound Free Energy HO A A reacts with B in the presence of sodium hydride to give C as a major product. NH₂ Ph B ŌSO₂CF3 NaH, THF a) Provide a detailed mechanism for the formation of C and draw it in the box above. ( C b) Draw the reaction coordinate diagram of that reaction. Indicate with an arrow the rate- determining step of the reaction then draw its transition state: Reaction Coordinate c) The reaction rate observed was 5 x 10-2 M.s¹ when the concentrations of A and B were 0.2 M and 0.1 M respectively. Determine the rate of this reaction when the concentration of A and B are now 0.3 M and 0.2 M respectively. Show your work.