QI: Illustrate the mechanism and products): (Both major and minor if applicable) OH CH3 + I) conc. H₂SO4/ heat Qll: Determine whether this order of basicity is correct, if it is not, place the structures from weakest to strongest. CH3CH₂MgCl > CH3OH NaOCH3 II) HC1/peroxides QIII: Select the correct reagent pair to complete the reaction: Illustrate the mechanism: Br 1) (CH3)2CHCHO II) CH3CHO III) CH3COCH3 + (CH3)2CHLI (CH3)2CHLI IV) CH3CH2CHO + CH3CH₂Li + (CH3)2CHCH₂Li (Aq Workup) H CH₂ H3C CH3 QIV: Determine the product of the reaction. Specify the chirality notation of both product(s) and reactants Illustrate the mechanism: Mg, Et₂0 CH3 OH III) HBr(Workup)

QI: Illustrate the mechanism and products): (Both major and minor if applicable) OH CH3 + I) conc. H₂SO4/ heat Qll: Determine whether this order of basicity is correct, if it is not, place the structures from weakest to strongest. CH3CH₂MgCl > CH3OH NaOCH3 II) HC1/peroxides QIII: Select the correct reagent pair to complete the reaction: Illustrate the mechanism: Br 1) (CH3)2CHCHO II) CH3CHO III) CH3COCH3 + (CH3)2CHLI (CH3)2CHLI IV) CH3CH2CHO + CH3CH₂Li + (CH3)2CHCH₂Li (Aq Workup) H CH₂ H3C CH3 QIV: Determine the product of the reaction. Specify the chirality notation of both product(s) and reactants Illustrate the mechanism: Mg, Et₂0 CH3 OH III) HBr(Workup)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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57. Arrange the compounds shown in decreasing (strongest to weakest) order of basicity. NH₂ NH₂ CF3 1 NH₂ OCH3 11 E ||| NH₂ IV
C. Arrange the following compounds in order of decreasing reactivity towards hydrolysis. In H3CO ΝΑΙ OH H₂N. ARL E ENE IYK D. Arrange the following chemical species in order of decreasing basicity. CH3 KAH YAS CI MIN BCS CH 3
Rank the compounds or ions in order of increasing acidity (or decreasing p?a).
3. Draw the structure(s) of the major organic product(s), for each of the following reactions. ELOH cat. H,SO, Br 1) 2 eq. Li b) 2) PHCHO 3) NH,C(ag) Ph = Phenyl 2 oq. Li c) NH,(1) 1) Hg(O,CCF3)z, (CH,);COH d) 2) NABH,, NAOH cat. NMO CH;C),
is thos reaction acid or base catalyzed? state why. ch2.