Rank the species in each group in order of increasing nucleophilicity. a. CH,, "OH, "NH2 b. H20, OH, "SH in CH3OH c. CH,CH2S", CH;CH2O¯, CH;COO" in CH3OH d. CH3NH2, CH3SH, CH;OH in acetone e. "OH, F", CI" in acetone f. HS, F", CI in CH3OH
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Q: which is more reactive in E2 reaction
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- Determine which reactions would occur (substitution, elimination, both, or neither). CH;CH,OH a. SN1 O b. E1 C. SN1 & E1 O d. SN2 е. Е2 O f. SN2 & E2 g. No reactionH30+ /A а. H3C-OH H3O+ /A b. CH,CH-OH РОСiз / рyridine C. HO. OH H2SO4 /A d.Draw the structure corresponding to each name.a. 3,3-dimethylpentanoic acidb. 4-chloro-3-phenylheptanoic acidc. (R)-2-chloropropanoic acidd. m-hydroxybenzoic acide. potassium acetatef. sodium α-bromobutyrateg. 2,2-dichloropentanedioic acidh. 4-isopropyl-2-methyloctanedioic acidi. 3,3-dimethylpentanenitrile j. 4,5-diethyl-2-isopropylnonanenitrile
- Draw the structure corresponding to each name.a. 3,3-dimethylpentanoic acidb. 4-chloro-3-phenylheptanoic acidc. (R)-2-chloropropanoic acidd. m-hydroxybenzoic acide. potassium acetatef. sodium a-bromobutyrateg. 2, 2-dichloropentanedioic acidh. 4-isopropyl-2-methyloctanedioic acid1c. What is the nucleophile in the following reaction? .Br CH;CO0 Na LO OCCH3 NaBr ld. What is the electrophile in the following reaction? Br CH;COO Na L0OCCH3 NaBr +Draw the products formed when p-methylaniline (p-CH3C6H4NH2) is treated with each reagent. a. HCl b. CH3COCl c. (CH3CO)2O d. excess CH3I e. (CH3)2C = O f. CH3COCl, AlCl3 g. CH3CO2H h. NaNO2, HCl i. Part (b), then CH3COCl, AlCl j. CH3CHO, NaBH3CN
- Draw the products formed when ethylene oxide is treated with each reagent. a. HBr b. H2O(H2SO4) c. [1] CH3CH2O; [2] H2O d. [1] HC ≡ C−; [2] H2O e. [1] −OH; [2] H2O f. [1] CH3S−; [2] H2OReagents a. C6H5CHO b. NaOH, ethanol h. BrCH2CH=CH2 i. Na* OEt, ethanol j. Br2, H* k. K* t-BuO c. Pyrrolidine, cat. H* d. H2C=CHCN e. H3O* f. I. CH2(CO2ET)2 -CH2CH2CN LDA m. heat g. ELOC(=0)CO2ET Select reagents from the table to synthesize this compound from cyclopentanone. Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda).Draw the structure corresponding to each name.a. 5-methylheptanoyl chlorideb. isopropyl propanoatec. acetic formic anhydrided. N-isobutyl-N-methylbutanamidee. 3-methylpentanenitrilef. o-cyanobenzoic acidg. sec-butyl 2-methylhexanoateh. N-ethylhexanamide
- 5. Classify the following reagents as either nucleophiles or electrophiles: Zn? CH;NH, , HS , OH; , CH;COOH , H,SO,Give the structure corresponding to each name.a. cyclohexyl propanoateb. cyclohexanecarboxamidec. 4-methylheptanenitriled. vinyl acetatee. benzoic propanoic anhydridef. 3-methylhexanoyl chlorideg. octyl butanoateh. N,N-dibenzylformamideb. d. a. a 6. Draw the organic product formed for each reaction. COOH COOH A [1] LDA [2] CH3CH₂l [1] Br₂. CH3CO₂H [2] Li₂CO3. LiBr. DMF 12 (excess) TOH CN NaH Br₂ (excess) TOH + CHI3